^ "^ Oi X ^ ? 2 ? -i^ nS "V^ ^ 01 t>4*. ^#(i ^# '^w€ ■> X - ^v/V.K?, ^^■* .#«-... T. • • ^ •.♦-i^-.- ;ii ,.' ■ -^'."'^ ;-^~>- ; •^ TRANSACTIONS OF THE MARYLAND ACADEMY « »« or SCIENCE AND LITERATURE. VOL. I. PUBLISHED BY THE ACADEMY. ■ V B OTA.NtCAL tiARDE^ BALTIMORE: PRINTED BY JOHN D. TOY. 1837. . n -^^'^T COMMITTEE OF. PUBLIC ATION. WILLIAM R. FISHER, R. EGLESFELD GRIFFITH, W. E. A. AIKIN. ^ INTRODUCTION. ci: The first successful efforts to organize an association in Baltimore, for the promotion of science and litera- ture were made in the year 1822. Similar associations had been previously contemplated ; some had actually gone into operation, but they soon disappeared after an ephemeral existence. The Maryland Academy of Science and Literature was opened under more favour- able auspices. A greater number of persons presented themselves willing to advance by their zeal the objects and the pursuits embraced within the scheme ; so that, at already an early stage of its organization, by the spontaneous liberality of some of its members and of other gentlemen, the academy found itself in posses- sion of an extensive collection of minerals, and an her- barium, the nucleus of a cabinet around which new materials might daily accumulate, and without which, no association of like character can expect to hold together, nor can in truth be said to have an existence. A strong appeal was then addressed to gentlemen of the learned professions in the city, and throughout the state, which was in some measure responded to, and iV INTRODUCTION. the number of contributing members became soon suffi- ciently large, to justify the step of procuring an apart- ment, where the meetings of the Academy could be held ; furnishingj at the same time a place of safe-keep- ing for the collection, which was beginning to acquire both extent and interest. Still there remained many difficulties to contend against. The limited pecuniary means at command, forbade the erection, or purchase, of a suitable edifice to be appropriated exclusively to the uses of the Academy. No building of a public nature could accommodate it ; and the frequent remo- vals thus occasioned, besides doing much damage to the collection, took away from it that character of per- manency, alone capable of rendering it an object of solicitude to the members. At length, however, the collection was removed to a spacious hall, in a public edifice, eligibly situated, where in a short time it increased so as to become worthy the attention of the naturalist. The principal accession which the property of the academy received at this period, consisted of a library, composed of standard works of reference, procured in part with a sum of money being the accumulated fund of a pre-existing society, which was thus transferred by its surviving members. The Academy stands indebted for this valuable acquisition to its then president, Robert Gilmor, Esq. who contributed besides, individually, by the donation of several costly and useful works. Other presents were also received from various quar- ters, the whole forming a collection of about eight hun- dred volumes, of the best publications in the different INTRODUCTION. V branches of the natural sciences. In the meanwhile, there was added to the cabinet an extensive series of geological specimens obtained from Germany, together with samples of the mineral formations occuring in this state. And subsequently, a considerable number of shells, recent and fossil, with numerous preserved indi- viduals belonging to other departments of natural his- tory, had been procured, all of which, whilst it gave evidence of zeal on the part of the few active members belonging to the academy, had become an object of interest to the scientific traveller, and proved that the natural sciences were not altogether neglected in Mary- land. But in an unfortunate hour nearly the whole of this valuable property was consumed by fire. Not discouraged by this calamity, the members of the Academy, acting under the authority of a charter obtained in the year 1826, have determined to re-orga- nize their society. Fully persuaded of the intrinsic importance of their scheme, its utility, the character it it may confer upon the city, as well as the general bene- fit that may accrue to the community by a co-operation of efforts to promote its accomplishment, they have set to work earnestly, not only to restore the Academy to what it was after twelve years of existence, but to re-establish it upon a basis of permanent prosperity. It is with infinite pleasure, therefore, that they find it in their power to announce, that in the short space ^ of one year since its revival, having obtained a com- modious set of apartments comprising one of large dimensions, the number of iheir collaborators having also greatly increased, their library already equals in Vi INTRODUCTION. extent, and surpasses in interest, that which they have lost, whilst the cabinet contains several thousand zoolo- gical, botanical, and mineralogical specimens. Every week brings new accessions to both ; so that, at this time the rooms of the Academy afford to the student of nature a place of resort, where he may pursue his favourite study with gratification as well as improve- ment. It is not the intention of the Academy, however, to confine its operations solely to the collection of natural objects. The members desire to extend its sphere of usefulness ; by submitting to the learned their intellec- tual labours, that have heretofore been compelled to seek a channel of publicity through scientific journals at a distance. It is now proposed to publish from time to time, a volume, or part of a volume of Transactions, which will embody detailed accounts of the peculiari- ties in the natural history of Maryland, new investiga- tions in the physical sciences, and original essays on subjects of general interest connected with them. An additional incentive to exertions will in this way be offered to the members; and, it is hoped, that the learned world will consent to accept the offering as an earnest of what is contemplated to be performed. To regulate as well as to facilitate the operations of the Academy the members have arranged themselves into sections, to which all donations according to their kind are referred, and are reported upon at the time, or at a succeeding meeting, by the chairman, or any other member to whom the subject may by him have been committed. The sections are denominated as follows : INTRODUCTION. vii Section 1. — Mathematics, Astronomyj and Physics, embracing Natural Philosophy and Mechanics.— Chair- man, L. Brajvtz. Section 2.— Chemistry. — Chairman, J. T. Ducatel. Section 3. — Mineralogy and Geology, including Phy- sical Geography, and the history and classification of Fossil remains — Chairman, P. T. Tyson. Section 4. — Zoology, embracing the comparative ana- tomy and physiology of animals — and further divided into six classes, viz : on the history and classification of Mammalia — Birds — Reptiles — Fishes — Insects, and Mollusca. — Chairman, R. E. Griffith. Section 5. — Botany, including Vegetable Physiology. Chairman, W. E. A. Aikin. In this state of things, a renewed appeal is confi- dently made to the American public, to similar institu- tions in this and other countries, and to the lovers of nature all over the world, to aid in furthering the objects of the Academy by contributing whatever they may have to spare in books, specimens of natural his- tory, and other objects of interest. As announced in a previous circular, 'the collections which the academy seeks to make, embrace all that can claim the attention of the literary and scientific. They include minerals, shells, fossils, specimens in natural science, books, coins, aboriginal antiquities, maps and documents illus- trative of the history, geography, or literature of any portion of the world, and in particular of Maryland. Unpublished barometrical or thermometrical observa- tions — descriptions of celestial or terrestrial pheno- mena and state statistics which have never been given Viii INTRODUCTION. to the world, are likewise among the means of infor- mation which it seeks to gather and make useful.' The academy addresses itself especially to its corres- ponding members, soliciting their aid in furnishing matter for the pages of its Transactions, to the accu- rate publication of which the most scrupulous atten- tion will be given. Subjoined is a list of the present officers, and of the resident, honorary and corresponding members of the academy. OFFICERS ELECTED JANUARY, 1837. President, JULIUS T. DUCATEL. Vice-Presidents, PHILIP T. TYSON, R. EGLESFELD GRIFFITH. Secretary, WILLIAM R. FISHER. Treasurer, DAVID KEENER. Librarian, J. H. aUINBY. Ctirato7's, JAMES GREEN, J. H. ALEXANDER, WM. EDWD. COALE, WM. RILEY. RESIDENT MEMBERS, Namei. P. Macaulay, J. T. Ducatel, Geo. Frick, Joshua I. Cohen, R. Gilmor, David Keener, Philip T. Tyson, Edw'd Dennison, I. Tyson, Jr. J. Pennington, George S. Gibson, Charles F. Mayer, Jos. W. Patterson, Geo. S. Sproston, Wm. Gwynn, Rich'd S. Steuart, J. I. Cohen, Jr. Charles Tiernan, T. Edmondson, Jr. Geo. H. Calvert, Geo. W. Andrews, H. Willis Baxley, A. B. Cleveland, J. H. Alexander, John P. Kennedy, J. H. B. Latrobe, J. Mason Campbell, Rev. Hector Humphreys, D. D. Wm. N. Baker, Wm. R. Fisher, Benjn. H. Latrobe, John R. W. Dunbar, Wm. E. A. Aikin, Lewis Biantz, Theodore Jenkins, James Green, Rich'd Wilmot Hall, Nathan R. Smith, John R. Hazlehurst, John B. Fitzgerald, Isaac Trimble, J. H. Q,uinby, 2 1821 1822 1823. 1824. 1826 1828, 1829. 1830. 1832. 1833. 1834. 1835. 183G.— , When elected. .—May 10. do. do. . — June 1. November 2. December 7. do. — December 2. -February 24. April 20. September 30. -January 19. February 2. do. do. February 16. do. March 2. -November 27. ■August 4. -January 21. -January 12. November 1. -March 28. September 12. do. November 28. do. •September 12. ■February 12. April 16. ■January 1. do. January 28. do. do. February 11. do. do. February 18. do do. MEMBERS OF THE ACADEMY. Names. When elected. Rich'd Caton, 1836.— March 3. John L. Webster, do. Wm. G. Thomas, do. Rev. John J. Chanche, April 7. Wm. Riley, do. Wm. Ed. Coale, do. Wm. Minifie, do. R. Eglesfeld Griffith, November 3 Cornelius McLean, do. John Fonerden, do. F. H. Davidge, 1837.— January 19. F. Chatard, do. Rev. John G, Morris, February 2, Samuel Annan, do. Samuel G. Baker, do. Rev. Geo. W. Burnap, February 9. John Prentiss, do. Thomas Buckler, do. Ramsay McHenry, March 16. J. Hanson Thomas, April 6, Alex. C. Robinson, do. J, C. Richards, do. R. S. Harlan, April 13. P. Rogers Hoffman, do. Wm. Geo. Read, May 10. Charles Bell Gibson, August 25. CORRESPONDING MEMBERS. Names. James E. Dekay, M. D. John E. Holbrook, M. D. Lardner Vanuxem, Wm. H. Keating, Gerard Troost, M. D. Christopher Hughes, Esq. Charles L. Bonaparte, Prince of Musignano. Wm. Darlington, M. D. Gen'l J. G. Swift, Edmund Ravenel, Elias Durand, Lt. Col. S. H. Long, Mifflin Coulter, M. D. Residence. New York. Charleston, S. C Bristol, Pa. Philadelphia. Nashville. Rome. West Chester, Pa. New York. Charleston. Philadelphia. U. S. Army. U. S. Navy. MEMBERS OF THE ACADEMY. XI Names. Leonard Osborne, M- D. "Edw'd H. Worral, M D. W. H. Davidson. M. D. I. Bruce, Esq. D. H. Barton, Esq. J. W. Greetham, M. D. J. Orville Taylor, Esq. A. Sidney Doane, M. D. Amos Binney, M. D. Charles J. Latrobe, Esq. Mendes I. Cohen, Esq. O. Hill, M. D. Charles Short, Esq. John L. Riddell, M. D. James E. Heath, Esq. Philip Williams, Jr. Esq. Charles B. Shaw, Esq. James Herron, Esq. Thomas Pennie, Esq. Z. Pitcher, M. D. Charles Cramer, Esq. Rev. John Backman, G. W. Clinton, Esq. H. A. Schroeder, Esq. W. L. Hawkins, M. D. Cons. I. I. de Macedo, Prof. Jameson, L. R. Gibbs, M. D. Rev. Virgil H. Barber, Matthew Carey, Esq. James C. Palmer, M. D. L. C. Gale, M. D. H. P. Sartwell, M. D. B. D. Green, M. D. Copley Green, M. D. Harris, M. D. Charles Lukin, Esq. J. Romeyn Beck, M. D. M. Henry Webster, Wm. H. May, M. D. J. Trowbridge, M. D. James Sullivan, Esq. Prof. C. D. Cleveland, Prof. James Hall, Prof. E. Adams, Henry Prentiss, M. D. James Renwick, LL. D. Residence. U. S. Navy. U. S. Arniy. Winchester, Va. do. do. Mount Vernon, 111. New York. do. Boston. England. Lewiston, N. Y. Lexington, Kentucky. Cincinnati, Ohio. Richmond, Va. Winchester, Va. Richmond, Va. do. Florida. U. S. Army. New York. Charleston, S. C. Canandaigua, N. Y. Mobile, Annapolis. Lisbon, Portugal, duito, S. America. Charleston. Conowingo, Pa. Philadelphia. U. S. Navy New York. Pen Yan, N. Y. Boston. do. do. Guayquil. Albany. do. Palmyra, N. Y. Buffalo, N. Y. Pembroke, N. Hampshire. Philadelphia. Troy, N. Y. Dartmouth College. Gloucester, Mass. New York. Xll MEMBERS OF THE ACADEMY. Names. Lieut. M. G. L. Clairborne, Lieut. A. K. Long, S. T. Laurason, M. D. G. Von Dem Busch, M. D. Signor Vilore Pecchioli L R. Jackson, Esq. James B. Rogers, M. D. * E. Geddings, M. D.* B. M. Byrne, M. D.* Robley Dunglison, M. D.* T. Phillips Allen,* Frederick Hall, Thomas P. Jones, Dr. Hornbeck, I. Pearson Smith, Willis Buel, Residence. U. S. Navy. do. do. Bremen. Pisa. Philadelphia. Cincinnati. Charleston. U. S. Army. Philadelphia. North Carolina. Washington. do. St. Thomas. South Carolina. Zanesville. HONORARY MEMBERS. Jose Silvestre Rebello, Charge d'affaires, Brazil. Right Rev. Bishop England, Thomas Cooper, M. D. LL- D. Benj. Silliman, MD. LL. D. William Maclure, Esq. Peter S. Duponceau, Esq. LL. D. John K. Miichell, M. D. J. N. Nicolet, Baron de Roenne, Minister resident, of the king of" Prussia, Don Ramon della Sagra, F. R. Hassler, Sir N. Carlyle, Com. De Figaniere, Charge d'affaires of the Q,ueen of Portugal, John J. Audubon, Charleston, S. Carolina. Columbia, do. New Haven, Con. Philadelphia, do. do. Royal Observatory, Paris. Washington. Madrid, Spain. Washington. London. Baltimore. * Formerly resident members. TRANSACTIONS OF THE MARYLAND ACADEMY OF SCIENCE AND LITERATURE. CLASS OF THE SCIENCES. ARTICLE I. Biographical notice of L. H. Girardin, LL. D. first Presi- dent of the Maryland Academy of Science and Literature. Louis Francois Picot, born in 1771, near Dreux, in the former province of Normandy, France, was educated at the Lyceum of Rouen. He is represented to have been, even at a very early age remarkal)ly fond of books, and was afterwards noticed for his assiduous apphcation to study. He has been heard to say himself, on those occasions when self-praise is not to be suspected, that he was considered by his teachers, who were pleased to encourage him by this avowal, as the best Latin scholar and poet of his class. On leaving the Lyceum he repaired to Paris at the invitation of M. Philippon de la Madeleine, by whom he was liberally patronized. There he became acquainted with most of the literary personages of the day, particularly with the celebrated author of Paul and Vir- ginia, and with the Abbe Barthelemy, the equally renowned author of the Travels of Anacharsis. To the former, young Picot dedicated his first otfering to the Muses, which, together with a translation in verse of Goldsmith's Deserted Village, was published, at the request of Bernardin de St. Pierre, by 3 18 BIOGRAPHICAL NOTICE Didot, of Paris. He likewise appeared as the translator of some pieces from the Italian of Casti, author of the '■Animali Parlanti.'' But, although these first effusions seem to have received the decided approbation of the public, and to have passed unhurt through the severe ordeal of literary criticism, his friends did not advise him to continue his pursuit after fame in this career. M. de la Madeleine had promised to obtain for him the situation of librarian to the king ; and by Bernardin de St. Pierre he was strongly recommended to direct his re- searches into history, the latter always terminating their con- versations together by advising him to write history, and refer- ing him, as a model, to the ingenuous translation of the Lives of Plutarch, by Amiot. In this apparently unobstructed way towards honours as well as emoluments, M. Picot was however suddenly ar- rested by the breaking out of the French revolution. M.-de la Madeleine his fast friend and patron, being attached to the royal cause, lost his influence, and with it all means of con- tinuing any efficient favours to his protege. M. Picot then returned to Rouen, and his opinions on the affairs of the time, being, as with the great majority of the enlightened population of France, in favour of a constitutional king, he took in their defence an active part in the editorial columns of the '■Journal de la Seine inferieure? He was, in conse- quence, soon arraigned before a revolutionary tribunal, to answer for some reflections contained in them, upon the execution of the king — an event that had then just taken place. These reflections, dictated by a noble and independent mind, did not suit tlie captious liberalism of the horde of venal politicians who had already commenced their abominable excesses, and he was compelled to abandon Rouen, whence he retired to his native village, on the eve of submitting to the public, what appears to have been, in his own estimation, his best claim to a literary renown — a tragedy in French verse, entitled Leonidas. At this time, the horror which filled every bosom through- out France, on hearing of the king's death, had inspired many persons, particularly among the younger part of the commu- nity, with a desire to avenge the honour of their country, by OF L. H. GIRARDIN. 19 rescuing from the hands of a tyrannical faction, the sceptre which it had usurped, and was wielding with so much oppres- sion. But such was the consternation spread throughout the country, such tlie distracted condition in (he affairs of every one, and tlie anxiety for personal safety, that there could be but little hope of devising any effectual mode of redress. The party of the Giro7idi?is, oppressed by the Chabots, Marats, and CoUot d'Herbois, was soon overpowered and fled. At this time also, the Marquis de Puisaye arrived at Caen, with a small reinforcement from England to General Wimpfen, who commanded the department of Calvados, This individual, who was a pure royalist, probably more attached to the cause of Great Britain than desirous of serving his own country, had, by his insulting and ironical deportment greatly displeased the fugitive Girondins ; yet he succeeded in collecting a band of three or four thousand men, at whose head he marched on to the attack of Paris. It was in this little army that M. Picot enlisted himself, no doubt with the most laudable motives; but the fate of this handful of young enthusiasts is well known — a detachment of gensfParmes soon put it to flight. The most obnoxious among them were consequently obliged to seek safety beyond their native shores, M. Picot, being one of them, fled in disguise to Brest, in company with his friend the now much admired poet Du Paty, where he embarked on board of a national ship that shortly afterwards arrived in Hampton roads. Unable to serve his country, and unwilling to connect his name witli the melancholy events of those days, M, P, de- serted his employment on the vessel that bore him to America. A French gentleman, who was the proprietor of a small farm in this State received him as a labourer — the present Marquis de Cairon, who had fled with him, being entrusted with the care of the poultry and swine. Then it was that M, Picot, from a false impression that the tyrants of his country could pursue him to this, changed his name to that of Lewis Hue GiRARDiN. As he already possessed a competent knowledge of the English language, he was advised to open a school, and in that capacity endeavoured to render himself useful to those who had extended to him their hospitality, Mr, Girardin's exemplary resignation, the moral courage which he evinced 20 BIOGRAPHICAL NOTICE in thus accommodating himself to his reverse of fortune, together with the extent of his information, attracted the notice of some well educated and intelligent gentlemen, and he was soon after invited to become a teacher in the college of George- town, D. C. on the recommendation of our late venerable fel- low-citizen, John Carroll, Archbishop of Baltimore. Such was that pious Prelate's esteem of Mr. Girardin's talents and virtues, testified to, moreover, in a letter which was gratefully and reverentially preserved by our deceased friend, that he strongly intreated him to receive orders: but it seems that this was not his vocation. He remained sometime a teacher in the catholic college of Georgetown, whence he removed to Virginia, where he presided at different times over several academies, enjoying the esteem and confidence of the first families of that State, whose children were placed under his charge. His character of a public teacher becoming now bet- ter known, and more generally appreciated, he received the appointment to a professorship in the university of William and Mary. It is from this place that he began to aspire to the lite- rary standing in his adopted country, which the disasters of a revolution had snatched from him in his native land. He com- menced the publication, in conjunction with a German artist by the name of Bos.sler, of a work entitled Amcenitates Gra- phicce^ to be edited in French and English, the prospectus of which sets forth that it has for its object, 'to form an instruc- tive and amusing collection of views, drawings of animals, plants, flowers, fruits, minerals, antiquities, costumes and other interesting objects ; selected with care and engraved upon drawings from nature, or the best representations of those objects ; with descriptions and suitable explanations in English and French : the whole with a view of inspiring young people of both sexes with a taste for useful and agreea- ble knowledge, to facilitate to them the study of it, and to enable them to become acquainted with the languages in which the descriptions and explanations are made. The descriptions and explnnations by L. H, Girardin, professor of modern languages, history and geography in the college of William and Mary — the engravings by Frederick Bossier, Williamsburg, September 12, 1S04.' This work was not OF L. H. GIRARDIN. 21 oontinucd, owing it has been understood to some disappoinl- luent on the part of the engraver. In 1805, Mr. Girardin connnenced the translation of the RevoUitionary Annals, or History of tlie French Revolution, upon the original manuscript of his friend, likewise a refugee to this conntry, M. Jean Henri de Croiseuil. This labour also remained unfinished. To the fifth part, which comprises the time when Buonaparte ascended the political horizon together with the first three years of his consulate, there is affixed an introduction by Mr. Girardin : it speaks in his favour, both as a writer and a politician. About this time also, he pub- lished his Latin poem De Monomachia, which did him credit as a moralist and as a votary to the Muses. In the eighth and twelfth numbers of the Old Baclielor, there are two letters by him, signed T. Lovetruth, that afford elegant specimens of his elevated tone of thinking, and of his sound ideas on the subject of education. Mr. Wirt has given the following testi- mony to their worth. 'As I read his letter,' he says, 'I felt in the style of his thinking the percussion of genius and virtue ; and I am convinced that literature and science stand at their back. Ex pccle Herculem. He should feel himself, bound to come forth for the good of our common country.' Of his second communication it is observed further ; 'Here follows a letter from one, to whom he feels well assured that he will never have to propose either condition or qualification: it is from his first correspondent and fast friend Lovetruth. Even the sorrows and tears of my old friend are full of virtue and instruction. He is a pen, 'To wake the soul by tender strokes of art. To raise the genius and to mend the heart.' ' In the 'Virginia Argus,' Mr. Girardin likewise published a series of literary and moral essays under the title of the 'Piii- lanthropist,' furnishing fresh evidence of the extent and ver- satility of his talents. The character of 'truth and decency, united to sound principles,' bestowed by a cotemporary upon the columns of the Richmond Enquirer, was acquired whilst Mr. G. was its joint proprietor and sole editor. About this time also he wrote a life of John Adams, at the solicitation of the classical Dennie, which was published in the Port Folio. 22 BIOGRAPHICAL NOTICE But we have now arrived at the period of Mr. Girardin's hfe, when to our admiration of his talents we are called upon to add our warmest sympathies in behalf of his misfortunes. The dreadful and too memorable catastrophe, which, in December, of the year 1811, plunged the metropolis of Virgi- nia into the deepest affliction, bore upon him most severely. In the conflagration of the theatre, at Richmond, he lost his wife and only son. So great a calamity on a man of ordinary sensibilities weighs indeed heavily enough; but to one, whose feelings are alive to the thousand impressions that pass unper- ceived by vulgar minds, how tremendous the thought of domestic happiness thus arrested in the full tide of its prospe- rity! How heart-rending the certainty, that what must ever be the dearest object of parental solicitude, has thus been vio- lently destroyed in its very bud ! It requires more philosophy than learning can bestow, to remain erect under so severe a shock. He sunk under its weight; his liealth rapidly de- clined; he was forced to suspend his professional exertions, and retired to the upper part of Virginia in quest of health and repose, neither of which he afterwards perfectly regained. The anniversary of this calamitous event was, to the last year of his existence, held by. him in melancholy remembrance. He refused at such times to accept of any friendly invitations, keeping himself in perfect seclusion. Yet, in this shattered state of both body and mind, he undertook and completed his continuation of 'Burke's History of Virginia,' one volume of which only has been published. Of the distinguished merit of this performance we have the guarantee of Thomas Jeffer- son, as well as that of the accomplished author of the life of Patrick Henry. The American Philosophical Society, has also testified to it by electing its author a member of that learned body ; and for similar considerations one of the univer- sities of this country, conferred upon him the title of LL. D. It was with such high recommendations that, invited by the trustees of the Baltimore college and determined by a desire to complete the education of his two daughters in the orna- mental branches, Mr. Girardin, came to this city having been unanimously chosen Principal of that institution. Though much engaged in the cares of this seminary of learning, that had been previously and for a long time labouring under OF L. H. GIRARDIN. 23 serious disadvantages, he did not altogether neglect his lite-* rary labours. He is known to have been the aulhor of 'Pulaski Vindicated,' — an energetic pamphlet written in reply to some supposed misrepresentations of the character of that distinguished warrior and patriot, made by Judge Johnson in his life of Gen. Greene. He had also prepared a course of lec- tures on Botany, for the Agricultural Society of Maryland, but was more particularly engaged at the time he was taken ill, in writing a life of General Lafayette, from documents furnished by the General himself It was but shortly after Mr. Girardin's arrival in this city, that proposals to organize a society for promoting the study of the natural sciences were started. To his concurrence in the plan originally suggested, his advice concerning the best man- ner of putting it into effect, and his subsequent active exer- tions as its President, the Maryland Academy of Science and Literature owes its existence. It is but a matter of justice, therefore, to record his extensive learning, his accomplish- ments as a scholar, his urbanity, and the high esteem in which he was held by his associates, on the very first pages that are offered to the public of the Transactions of the Society. Mr. Girardin's demise took place, whilst he still enjoyed the full vigour of his intellect, and was about to give further proofs of his usefulness in the promotion of science and litera- ture. But we bow with reverence and humility to the dispen- sations of a Divine Providence ; for such were the feelings of our venerated friend when he calmly resigned himself to the will of his Maker, on the 17th day of February, 1S25, in the 54th year of his age. j. t. d. 24 PHYSICAL GEOGRAPHY AKTICLE II. Outlines of the Physical Geography of Maryland, embracing its prominent Geological features. By J. T. Ducatel, State Geologist, i H ~i ^ 1 1 1 hi* ,^ i ^^ 1 i 1 ^ ^ t 1^ t '^ in 1 H •^ '^ »r > ^ a v^ -^ ■^ ■^1 8; s .9^ ^ o, -^ >s ^ •^ ols [D H a \ o-j -^ ro O (O N » c Zjx OI o '^a n i; : o -J ., rio ^ 12 c w — 1 4- 5i p : X CI ^O 00 . o ■n '35 ^_ r-i f-j h^ ^ »_. H o ^ *> ^r-I O Oi r?- Cr. K ^ "~ n 1^ 1 1 I 1 1 1 O c z H n w ^\ "^ .^ ? 11 " '■ ">^- ^if "l \\ ^ ■xj. -^r ^ Vf >^ OJ •+■- c;>i C" o fO o> H re -*■ M O" o —1 ^^*^ so CT. -) &■ ^■' _. Au. Road sides. A. spinosus, Linn. ^-i^. Au. © Road sides. A. lividus, Linn. g'. Ju. Road sides. Ambrosia trifida, Linn Tall Hogweed. g-y. Au. 4 — 8 ft. A. elatior, Linn. Hogweed. ^-j/. Ju. (v) 1 — 3 ft. Old fields. Ampelopsis quinquefolia, Mx. Creeper, g. Ju. \ Climbing. Amphicarpa monoica, Ell. b-w. Ju. Twining. Damp thickets. Anagallis arvensis, Linn. Scarlet Pimpernel, r. J. © 6 i. Andromeda mariana, Linn. w. J. \i 3 — 6 ft. Open woods. A. j9oZ(/bZta, Linn. r-w. M.. 13 18 i. Sphagnous swamps. A. arhorea, Linn. Sorrel tree. w. J. Tj 40 ft. Eastern Shore. A. paniculata, Ph. White Bush. w. J. }z 1 — S ft. Dry woods. A. racemosa, Linn. w. J. ^2 2 ft. Swamps. A. calyculata, Linn. ic. M. h 2 ft. Swamps. 8 58 fcATALOGtrE OF- Andropogon scoparius, Mx. Broom grass. Au. IJi 3 ft. Open woods. A. virginicus, Linn. Bent grass. Au. m 2 ft. Old fields. A.furcatus,Muh.\. Au. 2/ 2 — 4 ft. River banks. A. nutans, Linn. Beard Grass. Au. 11 3 — 6 ft. Sandy fields. Anemone virginiana, Linn. Wind Flower, g-w. Ju. 2/ 18 i. Meadows, A. pennsylvanica, Linn. ii>. J. ::>i 15 i. Meadows. A. aconiti- folia, Mx. A. dicJiotoma, Linn. wj. M. ^ 1 ft. Woods. Synonymous with A. pennsylvanica, Linn. A. nemorosa, var. quinquefoUa, Dec. Low Anemone, r-w. M. :^ 6 i. Open woods. A. thalictroldes, Linn. Rue Anemone, w. M. 2/ 6 — 10 i. Open woods. Angelica triquinata, Mx. Angelica, w. Au. 2/ 2 — 4 ft. Dry woods. A. atropurpurea, Linn. ^-to. Aug. 2/ 3 — 6 ft. Wet meadows. Anthemis arvensis, Linn. Wild Chamomile, w-y. J. 'S 6 — 12 i. Old fields. A. cotula, Linn. Mayweed, w. J. 10 i. Road sides. Tonic, vesicatory. Anthoxanthum odoratwn, Linn. M. 2/ 12 i. Meadows. Antirrhinum eZaiiwe, Desf. Creeping Snapdragon, b-w. Ju. (^ 1 — 2 ft. Old fields. A. Unaria, Linn. Toad Flax. w. 7j. Ju. 2/ 18 i. Roadsides. A. canadense, Linn. Flax Snapdragon, b. J. 2/ 12 i. Apios tuberosa, Ph. Ground-nut. j5. Ju. 2/ Twining. Meadows. Afocynvm. androsaemifolium, Linn. Dog Bane. r-w. Ju. 21 2 — 3 ft. A. cannahinum, Linn. Indian Hemp. ^-?/. J. ^ 3 ft. Open fields. A. hypericifoUum, Linn. g-w. J. 2/ 3 ft. This and the preceding species (if there are in reality two) have long troubled the botanist. Their close resemblance renders it difficult to find distinctive- specific characters. Aquilegia canadensis, Linn. Wild Columbine, r-y. Ap. IJ. 15 i. Rocks. Arabis sagittata, Dec. Wall Cress, w. J. S ? 2 ft. Old fields. A. ihaliana, Linn. Mouse-ear Cress, w. Ju. 6 — 12 i. Sandy fields. A. levigata, Dec. w. M. 21 1 — 2 ft. Hill sides. A.rhomboidea,?. Spring Cress, w. M. y. 12 i. Wet woods. A. ?yra/a, Linn. lo. Ap. I %> 10 i. Point of Rocks, Fred. Co. A. canadensis, Linn. w. J. y. 1—2 ft. Rocky banks. PLANTS AND FERNS. 59 Aralia spmosa, Linn. Shot Bush. y-w. Au, h 10 — 15 ft. Rocky woods. A. racemosa, Linn. Spikenard, tv. J. 2/ 3 ft. Shaded banks. A. nudicaulis, hinn. Wild Sarsaparilla. iv. M. 1J. 18 i. Woods. Arctium lappa, Linn. Burdock, r. Au. 11 Introduced. Arenaria serpylifolia, Linn. xo. J. © 6 i. Sandy fields, A. stricta^Mx. w. M. If. 6— 12 i. Rocky banks. A, lateriflora, Linn. lo. J. 11 6 i. Wet meadows. A. peploides, Linn. r-w. Ju. 21 10 in. Shores of the Chesapeake. A. canadensis, P. r- J. © 3 — S i. Brackish meadows. Probably synonymous with A. rubra Linn. Argemone mexicana, Linn. Prickly Poppy, y. Ju. @ 12 i. Rocky banks of Potomac in Fred. Co. Ari s TiDA dic/to/oma, Mx. Beard grass. Au. 1}. 12 i. Sandy fields. A. purpurascens, Foir. S. ^ 18 i. Sandy fields. A. gracilis, E\\. S. 21 IS i. Approaches the A. dicAofo/raa in cha- racters. Aristolochia serpenlaria, Linn. p. J. 11 12 i. Rich woods. Arnica nudicaulis, N. Leopard's Bane. y. Ju. 2/ 2 — 3 ft. Sandy woods. Aronia arhutifolia. Ell. Red Choke Berry, w-r. M. Ij 3 — 6 ft. Swamps. A. hotryapium, P. June Berry, w. Ap, Ij 8^ — 30 ft. Woods. A. melanocarpa, Tor. 70. M. \i 3 — 6 ft. Swamps. Artemisia canadensis, Mx. Wild Wormwood, to-y. Au. ;^ 3 ft. Arum dracontium, Linn, Green Dragon, g. J. 2/ 18 i. Low banks of streams. A. atrorubens. Ait. Brown Dragon. M. if Wet woods. A. triphyllum, Linn. Indian Turnip, p-g. to. M. 11 I — 3 ft. Wet woods. Arundo canadensis, Mx. Reed grass. Au. If. 3 — 4 ft. Low grounds. A. coarctata. Tor. Ju, 2/ 8 — 5 ft. With the last often in water. AsARUM canacfense, Linn. Wild Ginger, g-p. M. if 6 — 12 i. Rich woods. Root strongly aromatic. Asclepias syriaca, Linn. Milkweed, w-p. Ju. if 3 — 5 ft. Road- sides and waste lots. A. obiusifolia, Mx. p. J. if 2 ft. Open woods. A. phytolaccoides, Vh. w-g. Ju. If 2 — 4 ft. Shaded banks, A. purpurascens, Linn. p. Ju. if 2 ft. Rocky woods. A. variegata, Linn. r. r-zo. to. Ju. ;2;[ 1 — 2 ft. Open woods. A. incarnata, Linn. r. Ju. ^ 2 — 4 ft. Banks of streams and wet meadows. A. quadrifolia, Jac. p-w. M. if 1 — 2 ft. Open rocky woods. 60 CATALOGUE OF A. verticillata, Linn. Dwarf Milkweed, y-g. Ju. y_ 1 — 2 ft. Sandy fields. A. angustifolia, Ell. g-w. M. y. 19 in. Eastern shore. AscYRUM hypericoides, Linn. y. Ju. S 12 i. Sandy barren fields. A. amplexicaule, Mx. y. M. 11 Eastern shore. A. cruxandreae, Linn. Peterswort. y. Ju. 1^ Sandy barren fields. Asparagus officinalis^ Linn. Asparagus, y-g. J. 2/ 2 ft. River banks. AspiDiUM flcros/ic/ioitZes, Sw. Ju. -y, 12 — 18 i. Shady banks. A. marginale, Sw. Ju. 2/ 2 — 3 ft. Woods. A. intermedium, Willd. Ju. 2/ 1 ft. Woods. A. dilatatum, Sw. Ju. 2^ 1 — 2 ft. Woods. A. hulhiferum, Sw. Ju. ;^ 18 in. Rocky banks. A. asplenioides, Willd. Ju. 2/ 1 ft. Shady banks. A. fragile, Sw. J. 2/ 6 — 12 i. Damp rocks. A.tenue,Fh. AsPLENiuM ehemtm, Ait. Ju. 2/ 6 — 10 i. Rocky woods. A. melanocaulon, Willd. Ju. 2/. 3 — 6 i. Rocky woods. A. thelypteroides, Mx. Ju. 2J. 2 ft. Rich woods. A. ruta-muraria, Linn. Ju. 2/ 2 i. On rocks. A. rhizophyUum, Linn. Ju. 2/ 6 — 10 i. Damp rocky woods. Aster H^i^Zms, Linn. y-p. Au. 2/ 1 ft- Dry woods. A. solidaginiodes, Mx. zi». Au. 2/ 2 ft. Dry woods. A. subulatus, Mx. r/. p. Au. 2/ 1 ft. Brackish meadows. A. tenuifolius, lAnn. to. Au. 2/ 18 i. Dry woods. A. ericoides, Linn. z^?. ?/. Au. 2/ i — 2 ft. Rocky woods. A.Jlexuosus, N. y. tr-j?. Au. 2/ 1 — 2 ft. Brackish meadows. A. cornifolius, WWid. w. Au. 2/ 18 i. Woods. A. Tiuynilis, Willd, lo. Au. 7t 1 ft. Pastures. A.plilogifolius,V^[\\i\. 10. p. Au. 21 18 — 24 i. Open dry woods. A. undulatus, Linn. Z>. y. S. 2/ 2 — 3 ft. Dry woods. A. diversifolius. Linn. p. S. % ^ ft. Dry woods. A. paniculatus, Ait. 70. y. Au. J^ 2 — 4 ft. Dry fields. A. conyzoides, Willd. w. Ju. ^ 12 — 18 i. Woods. A. macrophyllus, Linn. w. h. Au. 21 18 i. Damp woods. A. OTTipZericawZMS, Willd. J. S. J^ 12 — 18i. Dry woods. A. prenanthoides,'\Y\\\(\.} h. S. 21- A. mutabilis,Linn. p.y. Au. 21 18 i." Woods. A. puniceus, Linn. b-p. Aug, ^ 3 — 6 ft. Wet woods. A, Tniser, Linn. io.b.S.2l 1 — 2 ft. Dry woods and fields. Avery variable species, including among its varieties three species of Aiton the A. divergens, A. diffusus, and A. pendulus, and perhaps others, A. alatus, {mihi) p. S,- y. Ju. 21 12—18 i. Damp shady woods. (1) PLANTS AND FERNS. 61 Astragalus carolinianus, Linn. w-y. Ju. 21 2 — 4 ft. Fred. co. west of the Catoctin Mts. Atriplex laciniata, hmn. ^. J. © 15 i. River shores. Atropa physaloides, Linn. iv-b. Jii. 2 — 3 ft. Ay^nx prcecox, F. deB. Dwarf oats. J. © 3 — 10 i. Sandy dry woods. A. elatior, Linn. J. ^ 3 ft. Open woods. Arrenatherum avenaceum, P. de B, Azalea nudiflora, Linn. Early Honeysuckle, r. M. ij 2 — 6 it. Dry woods. A. viscosa, Linn. ?p. J. Ij 3 — 5 ft. With the last. Baccharis halimifolia, Linn. Groundsel Tree. to. S. Ij Shores of the Patapsco. Baptisia tinctoria, Br. Wild Indigo, y. Ju. ^ 2 — 3 ft. Dry woods. B. coerulea, Mx. h. Ju. ^ 2 — 4 ft. Banks of the Potomac, Fred. co. Barbarea vulgaris, Br. Water Radish, y. M, ^ i — 2 ft. Wet meadows. Batschia canescens, Mx. Puccoon. ?/. Ju. J^ 6 — 10 i. Hills around Franklin. Berberis vulgaris, Linn. Barberry, y. M.. ^2 6 ft. Rocky woods. Betvla. populifolia. Ait. White Birch. Ju. h 40 ft. Rocky woods. B. papyr ace a. Ait. Paper Birch. M. \i 50 ft. Woods. B. lenta, Linn. Black Birch. M. Ij 40 — 80 ft. Low woods. B glandulosa, Mx. Scrub Birch. M. Ij 4 — 6 ft. Mountain swamps. BiDENs cernua, Linn. Water Beggar-ticks, y. Au. 1 — 2 ft. Wet ditches. B. chrysanthemoides, Mx. Daisy Beggar-ticks, y. Au. © 12 — 18 i. Wet. B. frondosa, Linn. Burr Marygold. y. Ju. 3 — 4 ft. Fence corners. B. hipinnata^ Linn, y. Ju. @ 2 — 4 ft. Rocky dry woods. BiGNONiA radicans, Linn. Trumpet Creeper, r. ?/. Ju. Jj Rich alluvial. Blitum virgatum, Linn. Slender Elite, r. J. 12 i. Fields. Boehmeria cyllndrlca, Willd. False Nettle, g, Ju. 21 1 — 3 ft. Damp woods. Botrychium virginicum, Swartz. Rattlesnake Fern. J. 2/ 1 — 2 ft. Damp woods. The B. gracile, Ph. evidently a smaller variety of this is often found with it. Brachyelytrum erectrum, P. de B. Ju. 21 2 — 3 ft. Rocky hills. Bromus secalinus, Linn. Chess. J. 2 — 3 ft. Corn fields. B. ciliatus, Linn. J. 2/. 2 — 3 ft. River banks. B. pubescens, Muhl. Broom grass. J. 21 2 — 4 ft. Wnr>r?-^. Ju. ^ 2—4 ft. Meadows. C. pubescens, Willd. g-io. M. J^ 12— 18 i. Dry woods. C.bijlora, Wr. g-y. M. 2/ 12—181. Rocky woods. C. majalis, Linn. Lily of the valley, tv. J. 21 6 1. Mountain woods. 9 66 CATALOGUE OF Convolvulus repens, Vahl. Wild morning-glory, to. p. J. 21 Climbing. Thickets and banks of streams. C. panduratus, Linn. Mechoacan. Man of the Earth, iv. r. Ju. ^ Trailing. Dry fields, C. spithamaius,Uim. lo. i. 2[. 9 — I2i. Dry fields. C. halaiiis, Linn. Sweet potato, lo. Jn. 21 Trailing. Sandy fields. C. piirpureus, Linn. Morning-glory, p. lo. r. J. © Naturalized. CoNYZA marylaiidlca, Mx. Plowman's- wort. p. Au. 1 — 2 ft. Swampy shores. C. cmjiphorata, Ph. p. Au. 2/ 3 ft. Is this distinct from the pre- ceding ? CoPTis trifolia, Sy. Gold Thread, w. M. 11 2 — 4 i. Swamps. CoRALLORHizA vema, N. ic-y. M. 21 5 — 6 i. Dry woods. C.muUiJlora^'N. p. Au. 21 S— 18 i. Dry woods. Coreopsis Za7iceoZai!a, Linn. y. S. 21 Low grounds. CoRNUs/oncZo, Linn. Dog-wood. lu. y. M. Tj 15 — 30 ft. Woods. Drupe scarlet. C. sen'cefl, L'h. w. J. ^2 S — 12 ft. Banks of streams. Drupe blue. C. aZ&a, Linn. iv. J. k 10 ft. Drupe while, C. paniculata^LPh. w. Ju. Tz C — 12 ft. Banks of streams. Drupe white. CoRYDALis glauca, Ph. g-y r. M. 12 — 18 i. Rich open woods. C. aurea, Willd. y. M. ^ — '- i- Rich meadows. CoRYLUS americana, Wr. Ilazle-nut. Ap. Ij 4 — S ft. Woods. Crataegus coccinea, Linn. Thorn, w. M. »2 6 — 10 ft. Woods. Fruit red. C. punctata, Ait. w. M. ^i 10 — 30 ft. Woods. Fruit red and yellow. C crus-galli, Ait. w. M. b 10 — 15 ft. Woods. Fruit red. Q. oxycantlia, lAnn. Hawthorn, lo. J. \ 8 — 10 ft. Hedges. Fruit red. Naturalized. Crotalaria sa^iiiflZis, Linn. Rattle-box, y. Ju. 8 — 12 i, Sandy woods. Cryptot^nia canadensis, Dec. w. J, 21 1 — 2 ft. Damp woods. Cucubalus stellatus, Linn. w. Ju. J^ 2 — 3 ft. Dry woods. Cunila mariana, Linn. Dittany, r-h. Ju. 21 8 — 12i, Dry woods, CuPHEA viscosissirna, Jacq. Wax Bush. p. J. G — IS i. Dry hills. CupRESsus ihuyoides, Linn. White Cedar. M. Ij 40 — 50 ft. Swamps. C. dt5/ic/ia, Linn. Cypress, M, Ij 60 -SO ft. Swamps. PLANTS AND FERNS. 67 CuscuTA americana, Linn, Dodder, w. Au, © A twining parasite on plants in damp shady places. Cymbidium pulchellum, Ph. Grass Pink. p. Ju. 21 12 — 18 i. Swamps. CvNOGLossuM officinale, Linn. Hound's Tongue. Tory weed. p. J. S 1—2 ft. Road sides. C. amplexicaule, Mx. w. b. J. % 12 — 18 i. Rocky woods. CypERus^auesceras, Linn, Au. ^ 6 — 8 i. Wet, C phymatodes^MnhX. Aw. 21 12 — 18 i. Low grounds. C mariscoides, EW. Au. 21 10 i. Sandy fields. C. strigosus, Linn. Au. 2^ 2 — 3 ft. Wet. CvpRiPEDiUM parvijloruni, Sw. g-y. M. 21 12 — 18 i. Rocky woods. C. pubescens, Willd, Yellow Ladies' Slipper, y. M. 12 — 18 i. Woods. C. spcctabile, Sw. w. p. J. 21 2 — 3 ft. Swamps. C. acaule, Ait. p. M. 21 1 ft. Damp woods. Dactylis ^?(?mera/a, Linn. Orchard grass. J. 21 2 — 3 ft. Meadows. Danthonia spicata, N. Wild Oats. Ju. 11 Dry woods. Datura stramonium, Linn. Thorn Apple, to-b. Au. (v) 2 — 4 ft. Waste grounds. D. tatida, Linn. p-io. Ju. (v) 2—4 ft. Waste grounds. A variety of the preceding. Daucus caroia, Linn. Carrot, to. J. % 2—3 ft. Road sides. Delphinium exaJtatum, Ait. Wild Larkspur, b. Ju. 21 2 — 4 ft. Rocky woods. I), consoliduin, Linn. Larkspur, b.w.r. Ju. (2> 1—2 ft. Naturalized. Dentakia diphylla, Mx. Pepper root. iv. M. j;/ 6 — 8 i. Wet woods. D. laciniata, Muhl. r-2o. M. 21 8 i. Wet meadows. Desmodium marylandicum, Dec. p. Ju. ^ 2 — 4 ft. Banks of streams. D. ciUare, Dec. ;?. Au. 21 1—2 ft. Woods. D. virldifiorum, Bk. ^-p. Ju. ^i 2—4 ft. Rocky woods. D. oUusum, Dec. p. Ju. 3;! 2—3 ft. Woods. D. paniculalum, Dec. p. Au. :y 2—3 ft. Woods. B. strictum, Dec. p. in. 21 1—3 ft. Sandy woods. D.nudiJlorum,'Dec. p. 3n. 21 Scape 1—2 ft. Woods. D. acuminatum, Dec. p. Ju. 21 2—3 ft. Woods. Diclytra cucullaria, Dec. y-w. M. :?/ 6-3 i. Shady river bottoms, D. canadensis, Dec. y-w. M. 21 6—8 in. With the preceding. 68 CATALOGUE Of DiERViLLA canadensis, Willd. Bush honeysuckle, r-y. J. h 2— "^ ft. Open woods. DiGiTARiA sanguinalis, P. Au. 1—2 ft. Road sides. B.Jiliformis, E\l. Au. . 1— 2 ft. Old fields. Galium /ri/idM/tt, Linn. w. Jn. 21 6— 12 i. Wet meadows. 70 CATAIiOGTJE OF G. tinctorium^ Linn. Wild Madder, lo. J. 21 1 ft- Wet woood. G. hrachiatum^ Ph. ro. Ju. 7/ 2 — 3 ft. Meadows. G. aparine, Linn. lo. J. % 3 — 4 ft. Damp woods and thickets. G. trijlorum, Mx. lo. Ju. 2/ 1 — 2 ft. Damp woods and thickets. G. circcszans,Mx. Wild Liquorice, p. J. 2/ 6 — 12i. Dry woods. G. lanceolation, Tor. p. Ju. 2J. 12 — 18 i. Dry woods. Gaultheria procumhens, Linn. Wintergreen. to. M. J^ 4 — 8 i. Rocky woods. Gaura liennis, Linn. r. y. An. S 3 — 6 ft. River banks. Gentiana saponaria, Linn. b. lo. S. 1 — 2 ft. Meadows. G. quinqueflora, Lk. w-b. Au. •£ 12 — ISi. Wet open woods. G. crinita, Frol. Fringed Gentian, b. S. ^ 1 — 2 ft. Swampy woods. Geranium mac«?a/«??i, Linn. Crane's-bill. _p. J. 2/. 1 — 2 ft. Fields and open woods. G. carolinianum, Linn. lo-r. Ju. S 1 — 2 ft. Rocky fields. G. puslUum, Linn. J. M. @ 12 — 18 i. Rocky damp woods. G. disseclum, Linn. r. J. (^ 3 — 12 in. Rocky open woods. G. robertianum, h'lnn. r. J. 10 — 15 i. Rocky banks. GERARDiA^^aua, Linn. False Foxglove, y. Ju. ^ 2 — 4 ft. Dry woods. G. glauca, Eddy. y. Ju. 2/ 3 — 5 ft. Open woods. G. j»wrj5tirea, Linn, p. Au. 6 — IS i. River meadows. G. tenuifolia, Yahl. p. Au. 6 — 12 i. Dry woods. G. pedicularia, Linn. y. Au. 2/ 2 ft. Point of Rocks. Geum strictum, Ait. y. J. 71 'H ft. Swamps. G. virginianu7n, Linn. to. Ju. 2/ 2 ft. Damp woods. G. album, Gmel. lo. Ju. 21 2 ft. Swampy woods. G. rivale, Willd. p. y. % M. 1 — 2 ft. Swamps. GiLLENiA irifoliata, Moen. Indian Physic, w. J. 21 2 — 3 ft. Rocky banks. Glaucium luteum. Scop. Horned Poppy, y. Ju. 1 — 2 ft. Rocky banks of Potomac. Glechoma hederacea, Linn. Ground Ivy. b. r. M. 21 6 i. Stem prostrate. Meadows. Gleditschia iriacantJios^ Linn. y-g. J. ^ 40 — 50 ft. Cultivated. GLYCERiA/wi/ajis, Br. Ju. 2/ 2 — 3 ft. Wet places in meadows. G. aculijlora, Tor. J. 2/ 2 — 3 ft. With the preceding. Gnaphalium polycepkahcm^ Mx. y-to. Ju. © 1 — 2 ft. Fields. G. decurrens, Ives. ?/-2«. Ju. 1 — 2 ft. Road sides. G. purpureum^hinn. p. Jn. 21 6 — 12 i. Rocky woods. G. uliginosum, Linn. y-io. Ju. 4 — 8 i. Muddy ditches. PLANTS AND FERNS. 71 G, ger7nanicujn,S. lo. Ju. 6 — 12 i. Dry liills. G, margaritaceum, Linn. ro-y. Ju. 21. 1 — 2 ft. Dry hills. G. plantagineumy Linn. Mouse-ear. r-zo. Ap. Jl 4 — lOi. Woods and fields. GoNOLOBUs Idrsulus^ RIx. j)- J"^!- 21 Twining. Damp thickets. GooDYEKK pubescens^^r. y-iv. Ju. 21 i- — 18 i. Rich woods. Gratiola virginica, Linn. y-to. Ju. 21 G — 8 i. Wet meadows. Habenaria cz/mr/s, Br. y. Ju. 11 1 — 2 ft. Upland swampy meadows. H. dllatata^ Hk. g. w. J. 21 1 — 3 ft. Damp woods and meadows. H. bracteuta, Br. g-w. M. 2/ 6 — 12 i. Shady damp woods. HJimhriala, Br. j). Ju. 2/ 1 — 2 ft. Wet meadows. * Hamamelis Dtr^m/crt, Linn. y. Oct. ij G — 12 ft. Open woods. HEDEom A pulegioides, P. Pennyroyal, p. J. © 6 — 12 i. Dry hills. Hedera helix, Linn. English Ivy. g-io. S. 2/ Stem rooting. On trees in wet woods. Helenivm. autumnale, Linn. y. Au. 2/. 3 — 5 ft. Banks of streams. Helianthus yrondosMS, Linn. y. Ju. 2/ 3 — 4 ft. Dry woods. H. trachelifolius, Willd. y. Au. 2/ 2 — 4 ft. Dry woods. II. angustifolius^hinn. y.p. Au. 2/ 2 — 5 ft. Upland swamps. H. strumosiis, Linn. ?/. Au. ^ 3 — 5 ft. Dry woods. H. altissiinus, Linn. y. Ju. 2/ 4 — S ft. Low grounds and swamps. H. decapetalus, Linn. y. Au. 2/ 3 — 4 ft. Dry woods. H. macrophyllus, Willd. y. Au. ^ 2 — 4 ft. Dry woods. Synonym of the last ? Heliopsis Icevis, P. y. Ju. ^ 3 — 5 ft. Low grounds. IIeliotropium eurojieum, Linn. w. Ju, G — 15 i. Rocky fields, near Point of Rocks. Helonias dioica, Ph. to. J. IJ. 1 — 2 ft. Rich woods and meadows. Hemerocallis /wZua, Linn. Day Lily. y. Ju. 2/ 2 — 3 ft. Na- turalized. Hepatica aculiloba, Dec. lo. b. Ap. 2/ 3 — 6 i. Woods. H. americana, Dec. to. b. p. Ap. ^ 3 — 6 i. Woods. Mere varieties of H, triloba, Willd, Heracleum lanatiim, Mx. Cow Parsnip, ic. J. 2/ 3 — 5 ft. Meadows, Hesperis matronalis, Linn. Garden Rocket. m>. Ju. 21 Natu- ralized. Heuchera americana, Linn. r. Ju. 2/ 2 — 3 ft Rocky woods. H, pubescens, Ph, r. i/, J, 2/ 2 ft. Rocky woods and banks. Hibiscus moscheutos, Linn. v\ p. Au. 2/ 2 — 5 ft. River swamps. 72 CATALOGUE OF H. palustris, Linn. p. Au. 2/ 2 — 5 ft. River swamps. Undoubtedly synonymous with the preceding, as the position of the peduncle and the form of the leaf is not constant, even in the same specimen. H. trionum, Linn. Flower of an hour. y-w. and p. Ju. (?) 1 — 2 ft. Cultivated fields. Naturalized. HiERACiUM ^rojio^ju, Linn. y. Ju. j^ 1 — 2 ft. Dry woods. H. venosum, Linn. y. Ju. 2/ 1 — 2 ft. Dry woods. Having never been able to find this plant with a glabrous or even smooth^^calyx, and a uniformly leafless scape, which are considered as the dis- tinguishing characteristics, I am more confirmed in the opinion, published many years since, that it is a mere stemless variety of the preceding extremely variable species. H. paniculaium., Linn. y. Ju. 2/ 1 — 2 ft. Dry woods. H. marianum, Willd. y. Ju. 2/ 18 — 24 i. Dry woods. HoLcus lanatus, Linn. J. 2/ 1 — 2 ft. Swampy meadows. HousTONiA ccerulea^ Linn. h. u\ M, ^ 4 — 6 i. Dry fields. H. longifolia, Willd. p. J. 2/ 6 — 12 i. Dry woods. H. purpurea, Linn. p. Ju. 11 6 — 12i, Banks of streams. HuMULus lupulus, Linn. Hop. g-y. Au. 2/ Twining. Hedges. Hydrastis canadensis^ Linn. r-w. Ap. 2/ 6 — 8 i. Rocky woods. Hydrocotyle americana^ Linn. g-w. J, 2/ 4 — 6 i. Damp woods. Hydropeltis purpurea, Mx. p. Ju. 2/. Ponds. Hydrophyllujm virginicum, Linn. lo. h. J. 2/ 1 — 2 ft. Shady damp woods. H. canadense, Linn. b. w. J, 2/ 1 — 2 ft. With the last. Hyosciamus m^er, Linn. Henbane, y.p. Ju. % 1 2 ft. Road sides, Hypericum ;)ro?i^cMm, Linn. y. 3. \ 1—3 ft. Banks of streams. H. perforatum, Linn. St. John's-wort. y. J. 2/ 1 — 2 ft. Road sides. H. corymhosum, Willd. y. J. 2/ 1—2 ft. Swamps and wet woods. R. parvijlorum, Willd. y. J. 2/ 6— 12 i. Low grounds. K. canadense, Linn. y. J. (v) 9 — i8i. Fields. H. virginicum, Linn. y-p. Ju. 2/ 1—2 ft. Bog meadows. H. sarothra, Mx. y. J. :y 3—6 i. Sandy fields. Sarothra gen- tianoides, Willd. Hypoxis erecZa, Linn. Star-grass, y. 5. 2/ 6 — 12 i. Woods. Hyssopus «e;?etoides, Linn. g-y. Sf g-p. Ju. 2/. 3 — 6 ft. Woods. H. scrophularifoUus, Willd. p. Ju. ^l 3—5 ft. ^ With the last, closely resembling it, and very probably a mere variety, as the form of the leaf cannot be relied upon, neither can the length of the style as this increases in length as the flower approaches maturity. PLANTS AND FERWS, 73 IcTODEs fatida, B\v, Skunk Cabbage, p. g. Ap. ^ Swampy- meadows. J LEX opaca, Alt. Evergreen Elolly. g-w. M. 1? 20 ft. Wet woods. Lmpatiens pallida, N. y. Ju. 2 — 4 ft. Wet grounds. I. fiilva, N. Touch-me-not. y, spotted. Ju. 2 — 4 ft. Wet grounds. Inula hehnium, Linn. Elecampane, y. Au. ^ 3 — 5 ft. Road sides. Ipomea lacunosa, Linn. w. p. J. © Twining. Low banks of Potomac. I. nil, Ph. Morning Glory, b. w. r. Ju. @ Twining. Banks of Potomac. Iris versicolor, Linn. Blue Flag. b. J. ^ 1 — 3 ft. Swamps. J. prismalica, Fh. b. J. ^ 1 — 2 ft. Margin of streams. IsANTHUs cosruleus, Mx. tc-b. Ju. (v) 6 — 12i. Gravelly shores and fields. IsNARniA paluslris, Linn. g. J. ^ Prostrate. Stagnant water. IvAfrutescens, Linn. ^. Au. I2 2 — 4 ft. Shores of Patapsco. JuGLANs nigra, Linn. Black Walnut. M. h 40 — 50 ft. Rich woods. J. cmeria, Linn. Butter-nut. M. h 40 — 50 ft. Rich woods. Jung us effusus, Linn. J. 21 2 — 3 ft. Wet grounds, J. tenuis, Willd. Ju. 21 1 ft. Road sides. J. nodosits, Muhl. Ju. 2/ 6 — 12 i. Swampy grounds. J. bufonius, Linn. Ju. 4 — 8 i. Moist ditches. J. polycephalus, Mx. Ju. 2^ 1 — 2 ft. Boggy meadows. J. acuminatus, Mx. Ju. 2/ 12 — 18 i. Bog meadows. JuNiPERUs commwrns, Linn. Juniper, g. M. ^ 5 — 10 ft. Rocky banks. J. virginiana, Linn. Red Cedar, y-"-. M. Ij 20 — 50 ft. Rocky- woods. J vsTici A. pedunculosa^ Mx. p. Ju. ij 1 — 3 ft. Water. Kalmia laiifolia, Linn. Laurel, w. r. J. \i 3 — 20 ft. Woods. K. augustifolia, Linn. Sheep Laurel, r. J. I2 2 — 4 ft. Dry woods. KoELERiA jyenns^ZuGMfca, Dec. J. 2/ 18 — 24 i. Rocky woods. K. truncata, Tor. J. 11 1 — 2 ft. Rocky woods, Krigia virginica, Willd. y. M. 4 — 8 i. Sandy fields. K. amplexicauUs, N. y. Ju. ^ 12 — 14 i. Open rocky woods. KuHNiA eupaloroides, Linn. False Boneset. zo. Au. 2/ 2 — 3 ft. Open woods, near North Point. Lactuca elongata, Muhl. y. J. Z 3 — 6 ft. Fields. hkyiivyi amplexicaide, Linn. r. p. M. © 6 — 10 i. Roadsides. 10 74 CATALOGUE OF h&.VRVs benzoin, Linn. Spice bush. g-y. Ap. h 4— 10 ft. Swamps. L. sassafras, Linn. Sassafras, y. M. I2 10 — 40 ft. Banks of streams. h. caroUnensis, Gates, y. J. \i 10 — 30 ft. Eastern shore, v. s. Lechea m?2or, Linn. g-p. Ju. 21 5 — 12 i. Dry rocky woods. Leersia virginica, Willd. Ju. y. 2 — 3 ft. Wet meadows. L. oryzoides, Sw. Ju. 2^ 2' — 4 ft. Swamps. Lemna trisuJca, Linn. Ju. Water in ditches. L. gibba, Linn. J. @ Stagnant water. L. polyrrhiza Linn. Ju. Stagnant water. Leontice thaUct?-oides, Linn. ^-y. M. ^ 1 — 2 ft. Rich woods, Leontodon taraxacum, Linn. Dandelion, y. Ap. ^ Fields. Leonurus cardiaca, Linn. Motherwort, w. r. Ju. 2/. 2 — 3 ft. Old fields. Lepidium virginicum, Linn. Wild Pepper-grass, w. J. 1 ft. Road sides. L. campestre, Br. y. J. © 1 — 2 ft. Cultivated fields. Leptandra virginica, N. re. Ju. J^ 2 — 4 ft. Dry meadows. Lespedeza capitafa, Mx. ?«-/>. J. 2/. 2 — 3 ft. Bushy fields. L. augustifolia, Ell. w-p. Au. ^ 2 — 3 ft. Rocky woods. L. polystachia, Mx. r-io. Ju. IJ. 2 — 4 ft. Dry woods. L. sessilijlora, Mx. r-p. Ju. 4/ 1 — 2 ft. Dry woods. L. violacea, P. ?'-p. Ju. ^ 1 — 2 ft. Dry woods. h. diver gens, Vh. p. Ju. J^ 1—2 ft. Dry woods. A variety of the last. L. procumbens, Mx. p. y, Au. 2/ 2 — 3 ft. Sandy woods. Liatris scariosa, Willd. p. Au. 2/ 2—4 ft. Dry rocky woods. L. spicata, Willd, p. Au. 2/ 2 — 4 ft. Bushy fields. LiGUSTRUJM vulgare, Linn. Prim. io. J. \ ^0 — 20 ft. Rocky woods, hii.iVM. 2^^iiicidelphicum, Linn. Lily. r-y. J. 21 1 — 2 ft. Meadows. L. canadense, Linn. Nodding Lily. y. r. Ju. 21 2 — 4 ft. Meadows. L. superbum, Lk. Superb Lily. y. r. Ju. J^ 3 — 6 ft. Meadows. LiNDERNiA atlenuala, Muhl. w-b. Ju. 4 — 6 i. Muddy shores, L. dilatata, Muhl. w-p. Ju. 4 — 6 i. Muddy shores. LiNUM virginlanum, Linn. Wild Flax. y. Ju. 1 — 2 ft. Bushy fields. L. usitatissimum, Linn. Common Flax. b. J, Fields. Natu- ralized. , LiQuiDAMBAR sly r ucijluo, Lmn. Sweet Gum. M. >2 15 — 40 ft. Low woods. PLANTS AND FERNS. 75 LiRioDENDRoN tuUpifera, Linn. White Wood. Tulip tree. American Poplar, r-y. J. l^ 40 — lOO ft. Rich woods. LiTHospERMUM arvcnse, Linn. iv. M. 8 — 18 i. Fields. Lobelia cardinalis, Linn. Cardinal flower, r. Ju. ^ 1 — 3 ft. Wet grounds. L. syphilitica^ Linn, I. Ju. 21 2 — 3 ft. Swamps. L. injlata, Linn. Wild Tobacco, b. Ju. S 1 — 2 ft. Fields and road sides. L. clayloniana, Mx. J, Ju. J^ 1 — 2 ft. Meadows. LoLivM perenne, Linn. Darnel. M. 21 1 — 2 ft. Meadows. LoNiCERA parvijlora, Lk. r-y. J. Ij Twining. Rocky woods. LuDwiGiA aliemifolia, Linn. y. Ju. ^ 2 — 3 ft. Grassy swamps. h.pilosa,Wr. y. Ju. 21 18 — 24 1. Grassy swamps. LupiNus perennis, Linn. Wild Lupine, b. p. M. 2/ 12 — 18 i. Sandy fields. LuzuLA pilosa, Willd. M. ^ 6 i. Moist woods. h. campestris, Dec. BI. 2/ 6 — I2i. Woods. Lycium barbarum, Linn. Matrimony vine. r. y. J. h Climbing. Naturalized. Lycopodium clavatum, Linn. ^. Ju. 21 Creeping. Pine woods. L. cojnplanatum, Linn. Ground Pine. g-y. Ju. 2/ Creeping. Pine woods. L. dendroideum, Mx. g'. Ju. 21 6 — 8 i. Woods. L. rupestre, Linn. Ju. ^ Rocky woods. L. lucidiihan, Mx. ?/. Ju. ^ 8 — 12 i. Low woods. Lycofus eiiropeus, Linn. iv. Ju. 21 1 — 3 ft. Wet places. h. virginicusjh'nin. w. J. 21 1 — 2 ft. Swamps. Lysimachia stricta^ Ait. ?/. Ju. 21 1 — 2 ft. Low grounds. 'L.thyrsiJlora^lAnn. y. J. 2/ 12 — 18i. Grassy swamps. L. qiiadrifoUa, Linn, ?/. J. 2/ 1 — 2 ft. Woods. L. ciliata, Linn. ?/. J. 2^ 2 — 4 ft. Shady banks. Maclura auranliaca, N. Osage Orange, ^i Naturalized. Magnolia glauca, Linn. Swamp Laurel, w. J. Ij 10 — 20 ft. Swamps. M. acuminata, Linn. Cucumber Tree. b-y. J. \z 50 — 70 ft. Allegany Co. Malaxis UUfolia, Sw. lo-y. J. 2/ 4 — 8 i. Damp rich woods. BLiLVA rotundifolia, Linn. iv-r. J. 2/ 8 — 12 i. Road sides. M. sylvestris, Linn. r-p. J. S 2 — 3 ft. Waste fields. Marrubium DwZ^are, Linn, llorehound. w. Ju. 2/ 12 — 18 i. Road sides. 76 CATALOGUE OF Martynia prohoscidea, Glox. Unicorn Plant, w-y. spotted. Ju. 1 — 2 ft. Banks of Potomac. Medeola rir^mica, Linn. y. J. % 12 — 18i. Rich, woods. Medicago lupulina, Linn. ?/. J. © 1 ft. Procumbent. Open grassy- woods. M. saliva, Linn. Lucerne Clover, p. Ju. ^ Cultivated fields. Naturalized. Melampyrum cmeWcanMOT, Mx. y. Ju. 6 — 12 i. Woods. Melissa officinalis, Linn. Balm. w. Ju. ^ Road sides. Natu- ralized. Melilotus officinalis, Lk. y. Ju. © 2 — 4 ft. Banks of streams. Sweet scented. M. leucantha, Dec. w. Ju. © 3 — 6 ft. Banks of streams. Sweet scented. Menispernum canadense, Linn. y-io. Ju. ^ Climbing. Banks of streams. Mentha horealis, Mx. Horse-mint. p. Ju. J/ 9 — 18 i. Wet places. M. tenuis, Mx. Spearmint, p. Au. 21 1 — 2 ft. Wet places. M., piperita, lAnn. Peppermint, p. Au. 21 1 — 2 ft. Naturalized. MiKANiA scandens, Willd. w. Au. 2^ Damp thickets. MiMULUs ringens, Linn. h. Ju. 2/ 1 — 2 ft. Wet grounds. M. alatus, Ait. h. Ju. J/ 1 — 2 ft. Wet grounds. MiTCHELLA repens, Linn. Partridge-berry, w. J. ^ A creeping evergreen. Woods. MiTEhLA diphylla, L'mn. Currant-leaf. w. Ap. 2^ 8 — 12 i. Rocky- banks. MoLLUGo verticillata, Linn. w. Ju. © Prostrate. Road sides. MoNARDA didyma, Linn. r. J. 2/ IS — 24 i. Meadows. M. o6'on^fl/a, Alt. r-J. Ju. 2/ 2 — 3 ft. Dry meadows. M. hirsuta. Ph. 20-5. spotted. Ju. j^ 2 — 3 ft. Rocky banks of Potomac. M. punctata, Linn. y. Au. IJ. 2 — 3 ft. Sandy woods. MoNOTROPA wni^ora, Linn. Indian pipe. w. J. 2/ 4 — Si. Shady- woods. Plant M'hite and leafless. MoRUs ruhra, Linn. Red Mulberry. M. Ij 15 — SO ft. Open woods, M. alha, Linn. White Mulberry. M. li 15 — 20 ft. Naturalized. MuHLENBERGiA di^Msa, Sr. J. 2^ 12 — IS i. Rocky woods. Myosotis joaZMS^ris, With. b. M, 21 12 — 18 i. Grassy swamps. M. ari'ensis, Sibth. w. M. 2^ 4 — 10 i. Sandy woods. Myriophyllum verticillalum, Linn. Ju. 2f. 9 — 18 i. Water. PLANTS AND FERNS. 77 "Nastvrtivm. palusire, Dec. y. Ju. © 12 — 18 i. Wet ditches. N. amphibium, Br. y. J. 2^ 1 — 2 ft. Wet ditches. I^ELUMBiuM Ititeum, Willd? Water Chinquepin. ij-w. Ju. ^ Water Eastern shore, v. s. Nemopanthes canadensis^ Dec. g-y. Ap. \ 3 — 6 ft. Rocky woods. Neottia ^raciZis, B\v. lo. Ju. 2/ 8 — 12i. Dry woods. N. cernua, Willd. g-io. Ju. 6 — 18 i. Moist grounds. Nepeta cataria., Linn. Catnip, r-w. J. ^ 2 — 3 ft. Old fields. "NiCAKDRA. physaloides,Ga.ert. h. Ju. 2 — 3 ft. Naturalized. NicoTiANA tabacum, Linn. Tobacco, w. r. Ju. Cultivated. N. rustica, Linn. Au. © Cultivated. N. TJanicw/aia, Linn. Au. Cultivated. NuPHAR advena, Ait. Yellow Water Lily. y. Ju. ^ Water. NvMPHiEA odorata^i Ait. White Pond Lily. 72 50 — 80 ft. Naturalized. PoRCELiA triloba, P. Custard Apple. Papavv. p. Ap, h 20 — 40 ft. Woods. PoRTULAccA oJerttcea, Linn. Purslane, y. J. Prostrate. Road sides. PoTAMOGETON nutans, Linn. g. Ju, ^ Water, Upper leaves floating. P. perfoliatiwi, Linn. g. Ju, 2/. Water. Submersed. P. lucens, Linn. g. J. ^ Water. Submersed. P. gramineum, Mx. g. Ju, ^ Water. Submersed. P. zosterifolium, Schum. g. Ju. J^ Submersed. PoTENTiLLA norveglca, Linn. Cinquefoil, y. J. lo — 18 i. Fields. F. canadensis, Liim. Five-finger, y. M. ^ 2 — 18 i. Procumbent. Road sides. F.comarum,I)ec. p. J. 21 12 — 18 i. Swamps. Comk-rvu palustre, Linn. Prenanthes alba, Linn. y-iv. Au, ^ 2 — 4 ft. Woods, P altissima, Linn. _p-?/. Au. ^ 4 — 6 ft. Woods. P. delloidea, Ell. J5, Au. 21 2 ft. Rocky woods. Prinos verticiUatus, Linn, False Alder, to. J. 13 4 — 8 ft. Swamps. Prunella t'2<7ifaris, Linn. J9. J. 21 6 — 12 i. Fields. Prunus virginiana, Linn, Wild Cherry, w. M. I2 30 — 60 ft. Woods. P. seroima, Ehr. iv. 3. \i 10— -20 ft. Woods. P. americana, Marshall. Wild Plum. ?«, M, Ij 10— 20 ft. Pteris aquiUna, Linn. Ju. J^ 1—2 ft. Woods. F. atropurpureaiLmn. Ju. ^ 6 — 12 i. Rocks. PuLMONARiA virginictt, Linn, b. M, ^ 1 — 2 ft. Low woods. Pycnanthemum incanum, Mx, r-?w. Ju, 2J^ 1 — 2 ft. Woods, Y.linifoVmm^Vh.. to, Ju, 2/ 1 — 2 ft, Open woods, F.lanceolatum,?\\. to. J. 21 12 — 18 i. Woods. Pyrola rotundifolia, Linn. to. J. 21 6 — 12 i. Woods, V.eUiptica,'N. to. 3. 21 6— 10 i. Woods, P, secunda, Linn. g-to. Ju, 21 6 — 8 i. Woods, T. asarifolia,Mx. g-to. Ju, 2/ 3— 12i. Dry woods. F. chhrantha, Sw.} g-to. Ju. 11 10 i. Dry woods. 11 82 CATALOGUE OF Pfrus coro7iaria, Linn. Crab Apple, r-iv. M. h 15—20 ft. Woods. QuERcus nigra, Linn. Black Jack. M. 1? 20—30 ft. Woods. Q. coccinea, Wm. Scarlet Oak. M. h 70—80 ft. Woods. Q. rubra, Linn. Red Oak. M. k 70—30 ft. Woods. Q. lannistcri, Mx. Scrub Oak. M. I2 4—8 ft. Dry hills. Q. alia, Linn. White Oak. M. h 70—80 ft. Rich woods. Q. prinos, Linn. Swamp Chestnut Oak. M. h CO— 70 ft. Low woods. Q. virens, Ait. Live Oak. M. h 40—60 ft. Said to grow on the sea-shore. q. phellos,U\m. Willow Oak. M. I2 40— 50 ft. Swampy woods. Q. tinctoria, Willd. Quercitron Oak. M. h 60—70 ft. Woods. Q. palustris, Du Roi. Pin Oak. M. h 40—60 ft. Swampy woods. q^. c7unqucipin,Fh. Dwarf Chestnut Oak. M. Tj 3— 6 ft. Barren hills. QuERiA canadensis, Linn. to. Ju. © 6 — 12 i. Dry woods. Ranunculus j:,MsiZZj. Ju. l2 2 — 4 ft. Meadows. S. opuUfoUa, Linn. Nine-bark. to. M. l2 8—6 ft. Rocky banks. S. corymhosa, Raf. r-w. Ju. ij 10 — 20 i. Mountain woods. S. aruncus, var. americana, Ph. Steeple-weed. w. J. 21 3 — 5 ft. Rocky banks. Stachys aspera^ Mx. Hedge Nettle, _p. Ju. 21 1 — 2 ft. Fields. Staphylea trifolia, Linn. Bladder-nut. y-to. M. Ij 6—10 ft. Bushy meadows. Stellaria media, S. Chickweed. w. M. X 1 ft. Procumbent. Road sides. S. pubera, Mx. w. M. 21 6 — 12 i. Damp woods. S. lanceolatum, Poir. zfj. J. 2/. 6 — 12 i. Meadows. S. Zon^j/bZia, Fries, w. J. 1}. 12 — 15 i. Meadows. Stipa avenacea, Wr. J. 21 1 — 2 ft. Open woods. Stylo sANTHEs elatior, Sw. Pencil Flower, y. Ju. J^ 9 — 12 i. Rocky woods. Stylypus vernws, Raf. w. J. 21 12 — 18 i. Meadows. Symphitum o^cinaZe, Linn. Comfrey. y-w. J. 2^ !■ — 2 ft. Natu- ralized. Tanacetum vulgare, Linn. Tansey. y. Ju. J^ 1 — 2 ft. Natu- ralized. Taxus canadensis, Willd. Yew. Ap. \i 3 — 6 ft. Rocky hills, Tephrosia rir^imana, P. r. y. Ju. 2/ 12 i. Dry woods. Teucrium canadense, Linn. Wood Sage. r. Ju. 2/ 1 — 2 ft. Damp woods. Thalictrum dioicum, Linn. Meadow Rue. w. M. 21 1 — 2 ft. Meadows. T. revolutum, Dec. w. Ju. 2/ 2 — 4 ft. Meadows. T. rugosum, Ait. w. J. 2/ 2 — 4 ft. Meadows. Thaspiujm atropurpureum, N. ^. J. 2/ 2 — 3 ft. Rocky banks. PLANTS AND FERNS. 87 T. barhinode, N. y. J. % 2—3 ft. Rocky woods. Thapsia trifoliata, Sp. Thesium umbellatum, Linn. g-to. J, 21 9 — 12 i. Dry woods. Thlaspi arvense^ Linn. ?t'. J. Fields. T.hursa-pastoris.lAim. w. Ap. 6 — 12 i. Fields. Thymus serpylltim, Linn. Wild Thyme, p. Ju. ^ Fields. TiARELLA cor^Zz/oZtrt, Linn. w. M. ^ 10 — 12 i. Rocky banks. TiLiA glabra, Vent. Bass-wood. y-io. J. k 20 — 40 ft. Woods. T. pubescens, Ait. ?«. J. k 30—40 ft. Woods. Tradescantia virginica, Linn. Spider-wort. b. M. 21 1 — 2 ft. Meadows. Trichodium laxijlorum, Mx. M. 21 18 i. Road sides. Trichostema dichotoma, Linn. Blue Curls, b. Ju. 6 — 12 i. Sandy fields. Trifolium repens, Linn. White Clover, iv. M. 11 Fields. T. pralense, Linn. Red Clover, r. M. % Fields. T. arvense, Linn. Hare's Foot. r-w. Ju. Dry fields. T. agrarium, Linn. y. J. © 8 — 12 i. Open woods. T. procumbens, Linn. y. J. 3—6 i. Pastures. Trillium erectiim, Linn. False Wake Robin, p. lo. M. :V 6 — 15 i. Damp woods. T. grandijlorum, Sal. w. M. 21 12 — 18 i. Rocky meadows. Triosteum perfoUaium, Linn. Fever Root. p. J. J^ 2 — 3 ft. Rocky woods. Triticum aestivum, Linn. Wheat. J. (v) 3 — 4 ft. Fields. Tripsacum dactyloides, Linn. Sesame Grass. J. 21 3 — 6 ft. Meadows. TussiLAGo/ar/ara, Linn. Colt's-foot. y. Ap. ^ 6 — 10 i. Low grounds. TypHA latifoUa, Linn. Cat-tail. Ju. 2/ 4—6 ft. Marshes. Ulmus americana, Linn. White Elm. Ap. I2 40—70 ft. Low grounds. V.fuha, Mx. Slippery Elm. Ap. k 20—40 ft. Woods. Uniola spiccr/a, Linn. Au, J/ 12 — I8i. Brackish meadows. Uraspermum claytoni, N. Sweet Cicely, w. J. 21 2 ft. Woods. U. hirsutum, Bw. w. J. 2; 2 ft. Woods. Urtic A ;3wmiZa, Linn. g. Ju. 8— 12 i. Damp places. U. dioica, Linn. Nettle, g. Ju. J/ 2 — 3 ft. Road sides. U. canadensis, Linn. Hemp Nettle, g. Ju. 21 3—6 ft. Damp shady places. Utricularia vulgaris, Linn. Bladder- wort. y. J. 2^ 6 — 3 i. Water. Ponds. 88 CATALOGUE OF I VvvhARiA perfoliata, Linn. Bell-wort, y. M. 11 8 — 12 i. Woods. ! V. grandiflora, S. y. M.. 2/ 9 — 18 i. Woods. j Vaccinium staviineum^ Linn. Deer-berry, w. M. \i 2 — 3 ft. Dry \ woods. Berries green. Y.frondosum, Linn, w. M. ^ 2 — 3 ft. Woods, Berries blue, 1 V. resinosum, Ait. Black Whortleberry, g-r. M. \ 2 — 4 ft. Woods. j Berries black. ; V. corymlosum, Linn. High Whortleberry, w. M. I2 6 — 10 ft. Swamps. Berries Black. | Valerianella radiata, Dec. Corn-salad, w. J. 8 — 18 i. i Meadows. i V. rho7niicarpa, (mihi,) h-w. J. iv) 4 — 6 i. Meadows. Valeria- j NELLA ccerulea, Eaton's Manual of Botany, 7th Ed. (6.) j Vallisneria spiralis, v. mnericana, Tor. Ju. 21 Water. Rivers. Veratrum viride, Ait. American Hellebore, g. J. 21 2 — 4 ft. • Swamps. Verbascum tJiapsus, Linn. Mullein, y. J. S 3 — 6 ft. Road sides. V. hiatfaria, Linn. Moth Mullein, p. y. J. S 2—3 ft. Road sides. ' Verbena spuria, Linn. h. Ju. 3i;J 1 — 2 ft. Decumbent. Road sides. ] V. hastata, Linn. Vervain, p. Ju. ^ 2 — 4 ft. Road sides. V. urticifolia, Linn. w. Ju, 21 2 — 4 ft. Road sides. j V. august if olia,M.x. b. J. 21 10 — 18 i. Sandy fields. " | Vereesina siegesheckia, Mx. y. Ju. ^ 3 — 6 ft. Rocky banks of Potomac. Vernonia novehoracensis, Willd. p. Au, 2^ 4 — 6 ft. Fields. Veronica officinalis, Linn, Speedwell, b. M. J^ 6 — 12 i. Pro- ' j cumbent. Dry woods, ' ■ V, serpyllifolia, Linn, b. M, 21 2 — 6 i. Road sides. I V. anagallis, Linn. Water Speedwell, b. J. 2/ 12 — 18 1. Wet places. ~ i V. scuiellata, Linn. h. J. ^ 9 — 12 i. Wet places. \ V. arvensis, Linn. tr-J. M. @ 3 — 8 i. Fields. ' Y. agrestis,hmn. b. M. 5 — 10 i. Fields. Viburnum prunifolium, Linn. Black Haw. w. J. ^2 8 — 15 ft. Woods. , Y . pyrifolium, Lk. w. M. b 5 — 10 ft. Low grounds. V. Zew^ago, Linn. Sheep-berry, w. J. h 8 — 15 ft. Woods. V. dentatum, Linn. Arrow-wood, w. M. h 6 — 12 ft. Damp thickets. PLANTS AND FERNS^ 89 V, puiescens, Ph. w. J. Tj 3 — 6 ft. Bushy fields. V. acerifolium^ Linn. Dockmackie. lo. J. ^2 3 — G ft. Dry woods. ViciA saliva, Linn. Vetch, h-p. J. 1 — 2 ft. Fields. V. craccct, Linn. b. .Ju. 2/ 12 — 18 i. Meadows. Viola cucullata, Ait. Blue Violet. Z». Ap. ^ 4 — 8 i. Meadows. V. palma/a, Linn. Z>. M. 11 4 — Si. Dr. Bigelow very properly considers this a mere variety of the preceding polymorphous species. Y . pedata, Linn. Bird-foot Violet, h. M. ^ 3 — 6 i. Rocky hills. V. ovata, N. b. Ap, 7/ 2 — 4 i. Dry woods. V. blanda, Willd. lo. p. Ap. % 2 — 4 i. Wet meadows. V. striata, Ait. i/-?i». J. 2/ 6 — 10 i. Wet meadows. V. canadensis, Linn. lo-h. M. 2/ 12 — 18 i. Damp woods. V. mulilenbergiana, Dec. h. M. j^ 6 — 8 i. Low grounds. V. jawSescens, Ait. Yellow Violet, y. Ap. 21 6 — 12 i. Woods. ViscuM d/c7io/owi7\ \ "- >. fc>^ ¥^. r*» I N ^ r ; "^ = ? ^ K - ^ « -■ cM ' 2 f /f ^ ?•/ «r > -3 9 > =( -a ^.F'/- ; 'y "fe '^' (pi M Rl l< I A N EJ AC fQ v!>? FROSTBURG COAL FORMATION. 93 topographical survey was made, under the direction of my colleague, J, H. Alexander, Esq. over a tract of country embracing more than twenty square miles. The streams before noticed, with their numerous tributaries, have formed ravines to such an extent, as to have removed perhaps two- thirds of the contents of the beds as they once existed ; they have however compensated for the waste, in furnishing facilities for the investigation and extraction of the valuable materials, without the expenses attendant upon deep mining and pumping; for the whole quantity of coal and iron ore at present known, amounting to about sixty feet of the former, and more than ten of the latter, may be extracted without the use of a shaft, and consequently without having to lift the water. George's creek, in its passage from Frostburg, cuts through beds of the series, whose aggregate thickness is about 1300 feet, and nearly reaches the inferior hmits. The Potomac has carried off nearly the whole of the principal beds of coal in the part of the trough through which it flows; the main coal or fourteen feet bed being 8 or 900 feet above the river, and is only found in small areas in the few hill tops, or spurs from the mountains on either side, which preserve that elevation. Jenning's run descends 100 feet to the mile, and as the strata rise considerably in the direction of its course, it cuts through the whole series within a few miles of its source. Braddock's run has carried off but a small portion, because it flows laterally, and soon runs out of the basin. In order to assist in ascertaining the structure of the region and its contents, sections were excavated on divers hill sides, and the position of the beds determined by levellings and measurements. One of these is selected, as the best calcu- lated to illustrate the character of the region. The position is about the centre of the formation on the south-eastern slope of Dug hill, a spur of the Savage mountain. The hill rises abruptly about 550 feet in elevation from the bed of George's creek, and then slopes off gradually 150 feet more. The surface of this last portion, is covered by detached fragments of coarse grit and sandstone, and no excavations were made into the strata thus covered ; but in descending, we first find 04 FKOSTBURG COAL FORMATION. the sandstone (No. 1,) in situ about 500 feet above the creek, and 1300 feet above the estimated inferior limits of the series, it is succeeded at 467 feet as follows : No. Thickness. Name. 2. 1.5 ft. Shale. 3. 2. Coal. 4. 31. Slate. 6. 18. Slate. 6. 4. Coal. 7. 6. Sandstone, (fine grained.) 8. 41. A covering of detritus, containing fragments of limestone, slate and sandstone. It is believed that one of the six feet beds of limestone which have been opened in the vicinity, in the same relative position exists here. Coal. Similar to No. 41. Slates and slaty sandstones appeared where the strata which had not suf- fered disintegration were reached. Hard sandstone. Slate. Shale. Coal. Shale. Coal. Shale, containing vegetable impressions. Coal, (the principal bed.) Shale. Clay containing nodules of iron ore. Slate. Sandstone, (exclusively siliceous.) Clay. Sandstone, (fine grained.) Nodular iron ore in clay. Detritus, except in the lower part, where fine grain sandstone appears in situ. Iron ore stratified sp. gr. 2.946. Coal, (called the 8 feet bed.) Shale. 9. 2. 10. 101. 11. 8. 12. 42. 13. 2. 14. 4.5 15. 2. 16. 1. 17. 12.5 18. 14. 19. 3. 20. 3. 21. 23.5 22. 31.5 23. 5. 24. 5. 25. 1. 26. 17.5 27. 1. 28. 7.5 29. 5. 31. 2. 32. 2. 33. 1. 34. 2. 35. 1. 36. 1.8 37. 1.8 38. 1.4 39. 1.3 40. 3. 41. 3. 42. 5. FROSTBURG COAL FORMATION. 95 No. Thickness, Name. 30. 1.5 Stratified iron ore, sp. gr. 3.255. This closely resembles some of the ores of South Wales, and has calcareous spar irregularly interspersed through the mass. Slate clay. Coal, Stratified iron ore, sp. gr. 3.541. Coal. Shale, Stratified iron ore, sp, gr, 3.473, Slate. Stratified iron ore, sp. gr. 3.374. Shale. Iron ore in layers, alternating with slate sp. gr. 3.374. Shale. Iron ore, similar to No. 40, alternating with shale or soft slate, 43. 4.5 Iron ore, similar to No. 40, alternating with hard slate. 44. 1. Coal. 45. Indurated ferruginous black slate, thickness un- known. The last brings us down to the surface of the valley, where the excavations were discontinued, and below this the beds have not been much examined ; it is, however, known that a bed of coal 6 feet in thickness crops out near the Potomac, about 600 feet below the 14 feet bed, and that several small beds occur above and below this 6 feet bed.* The coal of all the beds is analogous in some respects to that of Wales, and may be ranked among the dry coals, the volatile matters being 15 to 20 per cent.; the 14 feet bed appears to be free from sulphuret of iron, of which there are some slight traces in the smaller beds. The quality of those above the 14 feet bed has not been * Since the foregoing was written, I have met with a bed of limestone, slightly ferruginous and about six feet in thickness, situated about twenty feet below No. 45. Also one of greater thickness and free from iron, about fifty feet lower than the last. 96 FROSTBURG COAL FORMATION. ascertained; the coal of the 14 and 8 feet beds is of the caking kind, but the coherence of the pieces cemented together is so slight, that it may be readily broken on the grale, a circumstance that, when taken in connection with the fact that the coal of the 14 feet bed, does not make smoke or deposite soot in the chimney, peculiarly adapts it to the warming of apartments •, those below the 8 feet coal do not cake. The 14 feet bed is very uniform, wherever it has been opened, but the 8 feet bed does not present exactly the same appearance in any two dis- tant points; for instance, at the Dug hill section it is 7i feet without seams of shale ; H mile west it is divided by two beds of shale, each 1 foot in thickness — into three beds of coal each 3 feet thick, while three-fourths of a mile to the south-east of the section it is separated by 1 foot of shale into two beds of 4 feet each. In some parts of the district it has been called a 10 feet bed. The iron ores are such as are common to the coal forma- tions of Great Britain, being carbonate of iron, more or less mixed with argillaceous and calcareous matters, and contain- ing from 25 to 40 per ct. of iron. Casts and impressions of fossils, have not been found abundantly, and no marine remains have been met with. Among the vegetable remains, are the Glossopteris Phillipsii, calamites, and others not yet determined. The beds in the north eastern part of the formation, are more highly inclined on the side towards Savage mountain, than on Dan's moun- tain ; while the reverse is the fact in the vicinity of Dug hill, and in the south-western parts of the trough; but the dip no where exceeds 10°, and very rarely 2 or 3°. The shales, slates and limestones, are such as are common to the regular coal formations ; but the sandstones, as far as at present known, are less micaceous than usual. The millstone grit, upon which the European coal measures usually rest, has not been observed under this formation; or if it does exist, its thickness must be insignificant; but it seems probable that the formation was originally covered unconformably with the grit, because it appears to be the only rack on the summits of Dan's and Savage mountains, where it lies horizontally. Detached fragments of it are frequently seen on the present surface of the coal basin. FROSTBTTRG COAT. FORMATION. 97 The whole series rests unconformably on the old red sand- stone, which appears on tlie western side of Savage mountain, about 1400 feet from the summit, as represented in the sections in plate 2. It dips at an angle of about 20° under the coal rocks, and re-appears on the eastern flank of Dan's moun- tain, with a western dip. When first seen in the gap of Jen- ning's run, its inclination is also about 20°, but the strata curve upwards at a greater distance from the axis of the mountain, and become much more highly inclined. Among the fossils in the red sandstone, which are all marine, only the Producti were determined. Towards the western base of Dan's mountain, the sandstone alternates with red limestone, and finally gives place to the carboniferous, or mountain lime- stone, against which it rests conformably. Producti have also been met with in this limestone. In colour, it varies from brown to dark blue, and is cavernous: it is inclined at a high angle, and rests conformably upon the siliceous white sand- stone of Wills' mountain. The structure of this mountain, is well exhibited at the gap traversed by the waters of Wills' creek; an escarpment on the northern side, reaches an eleva- tion of about 900 feet above the creek, and on the western portion, is covered by a talus for several hundred feet from its base. The central portion of the mountain consists of old red sandstone, which like that under the coal series, is made up of alternations of moderately hard sandstone, and a softer variety passing into shale. When first seen on its western limits, it is highly inclined, and dips westwardly. The strata then bend over in the form of a flattened arch, and dip to the eastward, with an inclination of 12° or 15°, until they pass under the bed of tlie creek. It is covered by beds of the siliceous sandstone, before referred to, which are several hun- dred feet in thickness, and form the summit and flanks of Wills' mountain; on the western side, they are almost ver- tical, and then curving to the eastward, are nearly horizontal at the summit; on the eastern side, we find them bending down until they dip about the same as the red sandstone upon which it rests. At the base of the mountain, the limestone precisely similar to that which was mentioned on the western side, rests conformably upon this siliceous sandstone, and is 13 98 FROSTBURG COAL FORMATION. itself followed by a thick bed of shale, with a conforming stratification. It is very probable, that the form of Wills' mountain is due to a force acting from beneath, and that the carboniferous limestone, resting upon the flanks of the mountain, formerly constituted a continuous covering, whose upper limits may be represented in the manner which is seen by the dotted line a a a on the section. It may be readily conceived, that the portion now wanting, might have been removed in the course of time, when we take into the account the solvent power of carbonic acid, aided by the ruptured condition of the lime- stone. The greater amount of the elevation must have taken place before the coal series was deposited, because the eastern edges of the carboniferous rocks crop out on the eastern face of Dan's mountain near the summit, and the basin shape proves that there must have been rocks on the eastern side considerably higher than exist at present. Another evidence of the elevation having taken place before the coal era, is in the fact, that the coal series bears the strongest evidence of not having been disturbed by subterraneous movements. There is no appearance of a fault or dike; on the contrary, the same bed at a distance of fifteen miles, and at the inter- vening points, is found just where it should be if it had never been deranged by partial movements ; and we can hardly imagine that the upward motion was every where directly vertical so as to elevate the beds without the least derange- ment; the amount of elevation must have been at least 2400 feet, that being the elevation of the highest part of the old red sandstone. At the epoch of the completion of the coal formation, no mountains existed in this district where we now find Dan's mountain and the Savage. They are the result of denudation by water, which perhaps required many series of years, and a countless number of floods in the Potomac and Savage rivers and other streams to produce. COMPOSITION OF PRUSSIAN BLUE. 99 ARTICLE V. On the Composition of Prussian Blue, prepared from different oxides of Iron. By T. Phillips Allkn, Corresponding Member of the Maryland Academy of Science and Literature. [Read before the Academy, January 26, 1836.1 Is Prussian blue, prepared by decomposing a salt of per- oxide of iron with ferro-prussiate of potash identical with the Prussian blue obtained by decomposing a salt of joro^oxide of iron with ferro-prussiate of potash, and oxidating the pre- cipitate? This question has not yet been satisfactorily answered. Considering it worthy of investigation, I undertook a series of experiments to endeavour to determine it in my own mind. Many conflicting opinions have been advanced on this in- teresting subject. The observing manufacturer has always contended that to obtain a blue of first quality, it was necessary to precipitate the solution of ferro-prussiate of potash, with a solution ofjyro^o-sulphate of iron, and then to oxidize the preci- pitate by washing it with water, or in preference with acidu- lated water. The theoretical chemist, on the other hand, has advanced that the blue obtained in this manner was different from thai obtained by decomposing a solution of ferro prussiate of potasU with a solution of /peroxide of iron ; that the former is inferior to the latter in intensity of colour, and that it is not a neutral prussiate of iron, but is a sub-salt containing an excess of oxide of iron. Having had occasion to prepare some prussian blue on a large scale, I dissolved 300 lbs. of ferro-prussiate of potash, to which I added a quantity of solution of proto-sulphate of iron, containing 390 lbs. of crystallized salt. On testing the liquor after the precipitate had subsided, I found it contained a large excess of sulphate of iron; whereas, had the decompo- sition taken place as has generally been supposed, that is, had all the cyanogen in combination with the potassium of the cyanide of potassium and iron, combined with the iron of the 390 lbs. of proto-sulphate of iron, neither the proto- sulphate of iron nor the ferro-prussiate of potash should have been in excess; for I had employed the proto-sulphate of iron 100 COMPOSITION OF and ferro-prussiate of potash in quantities proportional to their equivalents, not wishing to have either in excess. Thinking that tliere might have been some mistake in the weight of the materials, I weighed carefully 300 grs. of ferro-prussiate of potassa and 390 grs. of crystalhzed proto-sulphate of iron, dissolved them separately and poured the solutions together, and obtained precisely the same result, a large excess of proto- sulphate of iron. Satisfied as to the accuracy of the experi- ment, I then dissolved 100 grs. of ferro-prussiate of potassa to ascertain how much crystallized proto-sulphate of iron was requisite to produce a complete mutual decomposition. After several trials, 1 found that S6 grs. were required, instead of 130 grs. the equivalent of 100 of ferro-prussiate of potassa; so that a portion of potassium is retained in the precipitate, which may be considered as a double cyanide of iron and potassium, containing much less potassium than the common prussiate of potassa. The presence of potassium in this precipitate was discovered by Proust, who did not ascertain its quantitative composition; but from this experiment it is evident that one- third of the ferro-prussiate of potassa is retained in combination with the precipitate, which instead of being FeUy^ or FP^, is llFe Cy -|- 4P (Jy, that is, a double cyanide of iron and potas- sium, in v/hich the cyanogen combined with the potassium, is just one-third of that which was originally combined with it in the ferro-prussiate of potassa. When this precipitate is washed with, water, the potassium it contains is dissolved, in the form of ferro-prussiate of potassa, as the iron becomes oxidated, but if the precipitate is washed with acidulated water, the precipitate becomes blue much sooner and no ferro prussiate of potassa is separated; but as the iron becomes oxidated, its capacity of saturation is increased one-third, and the hydro-ferro-cyanic acid combines with it, and the potassa resulting from the potassium, combined with the acid used to acidulate the water. To ascertain whether this was really the case, I dissolved 100 grs. of ferro-prussiate of potassa, precipitated the solution with 86 grs. of proto-sulphate of iron, and after the precipitate had subsided, I drew off the water, then filled up the bottle with water and added 16 grs. of >sulphuric acid, a quantity just sufficient to form a neutral t»RUSSlAN BLUE. 101 sulphate of potassa, if all the potassium combined in the pre- cipitate were to combine with it. The water was acid to the taste and reddened litmus paper, but the materials being left together five months, and shaken every day or two, the pre- cipitate became of a very dark blue, and the water no longer gave any indications of acidity, and was found to contain sulphate of potassa, instead of sulphuric acid. The next thing to be ascertained was to see how much of a salt of peroxide of iron was requisite to decompose 100 grs. of ferro-prussiate of potassa; for which purpose I dissolved 100 grs. of prussiate of potassa, took a given quantity of proto-sulphate of iron, to which I added the necessary quantity of sulphuric acid to constitute the per-sulphate, the iron was oxidated by adding nitric acid, then evaporating to dryness and redissolving in water. After several trials, I found that 100 grs. of prussiate of potassa required to decompose it, a quantity of per-sulphate of iron containing the same quantity of iron as that contained in 86 grs. of crystallized proto-sulphate of iron, that is to say, 86 grs. of proto-sulphate of iron converted into per-sulphate of iron were just sufficient to decompose 100 grs. of prussiate of potassa. From this we are led to conclude that prussian blue, made by decomposing prussiate of potassa with a salt of joro^oxide of iron, and washing the precipitate with acidulated water until it becomes completely peroxidated is identical chemically with prussian blue obtainedin decomposing prussiate of potassa with a salt ofjoe^'oxide of iron; but if the precipitate is washed with water only, it will contain an excess of oxide of iron, and in both cases if dried before it has become com- pletely oxidated, it will contain potassium or potassa as one of its constituents. Having incinerated some prussian blue made with a salt of protoxide of iron, and some made with a salt of peroxide of iron, I f)und that on washing with hot water the oxide of iron obtained from the incineration of blue made with a salt of protoxide of iron, the water became strongly alkaline ; wliereas on washing the oxide obtained from the incineration of blue made with a salt of peroxide of iron, the water became very slightly alkaline, from which I infer that prussian blue owes its beauty to the presence of a little potas- sium or potassa as one of its constituents. Berzelius states that prussian blue made with a salt of protoxide of iron differs 102 MINERALS OF MARYLAND. from that made with a salt of peroxide of iron, in being readily- soluble in water ; whereas that made with a salt of peroxide of iron is not soluble in water. I always succeeded in dis- solving both ; but it is true that the blue made with a salt of peroxide of iron requires much more washing than that made with a salt of protoxide of iron to become soluble. From the foregoing experiments it appears then, as Mr. Robiquet suggested in a memoir, published in the An?i. de Chim. et de Physique^ torn 44, that the difference we observe in Prussian blue may be attributed to the presence of potassium or potassa, for it is evident that the blue made with a salt of peroxide of iron cannot contain any potassium or potassa, and that made with a salt of protoxide of iron does contain some, unless perfectly oxidated by washing for a long time with acidulated water. ARTICLK VI. A descriptive Catalogue of the piincipal Minerals of the State of Maryland. — By P. T. Tyson. [Read before the Academy, March 9, 1637.] For greater convenience and to avoid repetition in noticing localities, the State will be divided into six districts. The first, embracing more than half of its territory, which lies south-east of a line drawn from Washington through Balti- more, Havre-de Grace, and Elkton, will be called the Hide-water district.'' Its north-western portion, comprising a narrow belt whose edges are not yet defined, is believed to belong to an upper secondary series, and rests upon the primary rocks of the second of our divisions. It is covered on the south-east by the remainder and larger portion of the first district, con- sisting of the great tertiary deposiles of the United States, which constitute nearly one-half of the territory of the State of Maryland. This region abounds with organic fossils, but its mineralogy possesses little interest. It consists of sands, clays, gravel, and loam (in many places abounding with fossils) and in ihe secondary portion some small beds of MINERALS OF MARYLAND. 103 ferruginous sandstone, which passes into a coarse conglome- rate, composed of siUceous pebbles with a ferruginous cement. Bog iron ore forms extensive deposites in the northern parts of Somerset and Worcester counties; indeed its formation is still in progress. It is smelted at the Naseongo furnace. Phosphate of iron occurs in crystals lining the cavities of the bog ore, and of course impairs the quality of the metal. Sulphate of lime in crystals is found in many places, but most frequently within the tertiary region. An interesting locality occurs on St. Mary's river, in a bed of clay of a bluish gray colour and very siliceous. The upper portion of the clay abounds with fossil shells, above which there is a considerable covering of ferruginous sand and gravel, containing lignite and iron pyrites. The spontaneous oxidation of the latter pro- duces sulphate of iron, which in its descent by percolation is decomposed by the carbonate of lime of the shells, and pro- duces the groups of crystals of sulphate of lime, which are mostly to be seen below the shells. Near the mouth of the Patuxent, there is another and similar natural factory, but the form of the crystals differs. Those on the St. Mary's river are all grouped together at one of their ends ; frequently eight or ten of them in a group are so arranged as to radiate from a central point, and the flattened prism sometimes six or seven inches long is lessened in thickness outward from the radiating point so as to assume a lanceolate form. The Patuxent specimens are grouped in a similar manner, but the prisms are shorter, more perfect on their sides, and are concave on their outer terminations. Quartz is found frequently constituting the casts of fossils, both animal and vegetable, and is usually of a coarse impure variety ; but in one locality Professor Ducatel met with a specimen of silicified wood, partly composed of fine blue chalcedony. Amber* exists at Cape Sable on the Magothy river. Lignite at the same place; and also, Sulphuret of irofi, which in connection with the lignite forms an extensive deposite and furnishes the material for a large manufactory of alum and copperas. The amber is * Dr. Troost. 104 MINERALS OF MARYLAND. opaque or faintly translucent, and varies in colour from brown to dull yellow. The sulphuret of ii^on is either crystallized or takes the form of wood, the structure of which may be seen. In that part of the district nearest the primary rocks argil- laceous carhonate of iron exists in abundance. It is in the form of nodules, varying from a few inches to several feet in diameter, of a gray colour, and has a compact structure when it does not embrace sand. The cavities of the nodules are often lined with crystals of pure carhonate of iron, which in most instances are so small and confused that their form cannot be determined ; they approach nearest to that called mixte by Haliy. The composition of these nodules in many localities is gradually changed into hydroxide of iron; by acquiring an additional portion of oxygen and combining with water. The carbonic acid being liberated forms bicarbonates of lime, and magnesia or manganese, if these earths be present. The soluble bicarbonate of lime, meeting occasion- ally with sulphate of iron resulting from the oxidation of pyrites, which is sparingly found in the iron ore deposites, produces the small crystals of sulphate of lime occasionally observed in the cavities of the nodules. The structure of the nodules is changed as well as the composition, but the ex- ternal form remains unaltered. Tlie oxidation commencing at the surface and proceeding inwards produces a series of con- centric layers. The composition of the crystals is also changed, so as to present us with hydrated peroxide of iron, whose crystalline form is that of the carbonate of protoxide. These ores were extensively smelted before the revolu- tionary war, and the greater part of the iron exported to England. They now furnish to three furnaces the material for producing a very superior metal. The scarcity of fuel prevents their being more extensively worked.* The second division consists of primary rocks, and ex- tends north-westerly from the first to Parr'^s spring ridge y where the rocks begin to assume the character of transition. This ridge passes through the northeast part of the new county of Carroll, and running south-southwest reaches the Potomac * Bruce's Mineralogical Journal, vol. i. p. 323. MINERALS OF MARYLAND. 105 river between Rockville and the mouth of Seneca creek. The principal rocks of this division are granite, gneiss, and mica slate in all their varieties, besides hornblend rocks, primary limestones, serpentine primary argiilite, talcose and chlorite slates, &.C. Quartz is of course abundant, and although it frequently occurs in crystals, fine specimens are rarely obtained. The largest crystals are found in the part of the granite and gneiss region, situated between the Patapsco river and the head waters of the Little Patuxent. Mr. Gilmor* mentions a fragment of one weighing nine pounds. These crystals are mostly of the smoky variety and often only semi-transparent. Trans- parent and limpid crystals have also been found in this and other localities. Chalcedony^ jasper^ hornsionc, and agate exist in several places, and mostly in connection with the hornblend and ser- pentine rocks ; good specimens of the two former are frequently found, but the finest chalcedony occurs in a primary limestone, 15 miles north from Baltimore; it has a smooth uniform aspect, a beautiful sky-blue colour, and is highly translucent. Fetid quartz also occurs in the primary limestone. The felspar of this district is mostly of the ordinary kind, and in some localities constitutes almost the whole of the granite. On the Baltimore and Ohio rail road, 9 or 10 miles from this city, large veins of a granite of this kind are protruded from below into both the gneiss and hornblend rocks. Occasionally specimens of the felspar have a regular crystalline structure, so that laminse of several inches in length may be obtained by cleavage; the colour is mostly dull white or yellowish white and salmon, but sometimes greenish. Mr. Gilmor notices crystals of felspar in the gneiss on Jones' fulls. Compact felspar^ embracing small imperfect crystals of quartz and specks of specular oxide of iron, form a rock that may be ranked with the weissteiti of the Germans. It occurs just where the Patapsco passes out of our primary division. Afi aggregate of quartz and felspar, both white and crystal- line, occurs on Jones' falls, 8 miles from Baltimore, containing minute prisms of tourmaline. It lies on the edge of the lime- * Bruce's Mineralogical Journal, vol. i. p. 323. 14 106 MINERALS OF MARYLAND. Stone, and so closely resembles it when seen from a short distance that it has elsewhere been described as litnestofie con- taining crystals of hornblend. It constitutes the leptinite of Brogniart. Mica in nearly all its varieties occurs in many places, and it is much to be desired that the different kinds should be in- vestigated, the more especially since the very interesting optical properties of this subgenus have been discovered. For our pre- sent purpose, it is only necessary to notice a few of the most interesting localities. On the Patapsco (the ^prismatique and bitiaire'') crystals of Haliy occur in large grained granite. On Jones' falls, 2h miles from the city, in a similar granite, pris- matic crystals abound, but their sides are much obliterated. One remarkable property of these crystals is that when viewed through the sides of the prism, they are translucent, even if more than one inch broad; yet they are perfectly opaque across the laminas, when less than the twentieth of an inch in thickness. In the same vicinity, the mica in a coarse granite exists in masses of a cuneiform shape of considerable size and with a peculiar structure, which may be understood by sup- posing the annexed diagram to represent a section through the mass. The lines represent the laminas, although they are not so uniform, but are partially interlaced. A-^^^^^^^^^^^^J Upon separating a portion of the laminse and holding them up to the light, lines of a dark colour appear, forming part of two or more sides of a regular hexahe- dral figure, whose centre would be at the apex of the wedge, marked (A). It is probable that the form of the pieces is the result of the operation of a regular law of crystallization, which has not been developed. In another spot in the same vicinity, mica of similar form embraces jorecioMs garnets, whose crystallization has been in- terrupted by the plates of mica, so as to have produced flat crystals ; some of which are nearly a quarter of an inch broad, the thickness is variable, some not being thicker than writing paper. They have not been flattened by pressure while soft, MINERALS OF MARYLAND. 107 because their edges show portions of the faces of symmetric crystals; their form is just what it would he if a perfect crystal were cut by tlie lapidary on any two opposite sides until it was very thin. Garnets occur sparingly in the granite and gneiss, but abound in the mica-slates, some of which contain so large a proportion and are of such an extent that the aggregate de- serves a specific name. Near the Gunpowder river, 14 to IG miles north-north-east of Baltimore, this garnetiferous mica- slate may be traced for two or three miles. The forms are (primiiif and trapezoidal) of Hauy, and the prismatic or elongated primitive crystals. Garnets of a large size occur in a disintegrating mica-slate, 3 miles east of the Gunpowder, frequently two inches in diameter; but they are very ferruginous and opaque. Tourmaline of the common variety occurs in the granite, gneiss, and mica-slate, and occasionally fine specimens are obtained. The yellow and brown varieties occur in the lime- stone. Sp/icne is sparingly disseminated in souk; of the Fatapsco granite. Beri/l has been found in the granite and in the granite veins of the gneiss, in large crystals. Phosphate of lime occurs in similar situations. Sulphuret of iron rarely occurs in the granite, but more frequently in the gneiss, and presents many varieties of crys- talline forms. Pyritous copper exists in small isolated grains in the granite and hornblend rocks on the Fatapsco. Of the minerals hitherto noticed in the granite, all except the sphene also occur in the gneiss. And there are many others in the latter rock which have not yet been seen in the Maryland granites. One of the most interesting localities in the gneiss is about 1| mile from Baltimore, on Jones' falls, where Dr. Hayden first noticed the following Uiinerals. Chabazie, (primitif) or Haydenite. Zeolite^ (pyramidal) and radiated. Sulphate of baryta^ (form indeterminate.) Sulphuret of iron ^ in crystals of divers forms. Carbonate of iron ^ (lenticular.) 108 MINERALS OF MARYLAND. These minerals exist in a seam of hornblend, from one to four inches thick; and in the adjoining gneiss, there are cavities whose surfaces are studded with crystals, mostly of chabazie and zeolite, furnishing beautiful cabinet specimens. The crystals of chabazie are transparent when perfect, but are found in every stage of decomposition, which first renders them opaque and finally they fall to powder. The crystals of zeolite are transparent, and of a fine honey yellow colour; the radiated variety is opaque and light yellow. It is much to be regretted that a disagreement between the two owners of the quarry should prevent either from working at this spot, which has been untouched for several years, and the quarrying is not likely to be resumed. The seam ap- peared to be increasing in thickness when the operations were suspended. Sulphureis of zinc and lead were found in a small vein near the locality of chabazie, but as it was not worth working, it has been covered by the refiise from the quarry. Graphite occurs 16 miles from Baltimore, on the Gun- powder, it is lamellated and very pure. Sulphuret of molybdenum has been met with near the last, in laminated masses more than one inch broad. Magnetic oxide of iron occurs in small quantities in several Jocaliiies. Titaniferous oxide of iron ox fer-titane occurs in abundance in the gneiss of Harford county, and is smelted at two estab- lishments. It is magnetic and possesses polarity. The common magnetic oxide of iron is disseminated in large octahedral crystals in chlorite-slate, near the 'Rocks of Deer creek,' in the same county. It also occurs in an aggre- gate of chlorite and quartz, near the Forks of the Gunpowder river, 25 miles north from Baltimore, and is associated with Pyritous copper, (in grains.) Sphene, in very large crystals : and Pycnite. The specular oxide of iron is very rare. Peroxide of manganese has been worked in Montgomery county. It occurs sparingly in other places. The mica-slate is variously mixed up with the granite and gneiss, but towards the north-western edge of the granitic range MINERALS OF MARYLAND. 109 it constitutes the principal rock. It has hitherto furnished but few species of minerals and none possessing much interest. Mica of course is abundant, and also Garnets^ SiauroHcle, and Cyanite. The most important localities of garnets have already been mentioned ; the staurotide and cyanite are abundant, particu- larly the former ; large crystals of each are common, but mostly imperfect. 1 have a crystal of staurotide, 1 inch thick and 3^ inches long. At Scott's mills, IS miles north from Baltimore, magnetic oxide of iron is disseminated in large proportion in the mica- slate, accompanied by cyanite. The primary limestone of this region occurs in tiie gneiss and mica-slate, and at one place in hornblend rock; it most usually constitutes the surface of the valleys and in no instance forms a hill oi any magnitude. It frequently appears as a large nest or isolated mass embraced by the other rocks. The most important localities are from S to 20 miles north to west from Baltimore, where it forms the surface of a number of valleys which are mostly connected together. In some valleys where stratification is visible, it is usually nearly horizontal and the rock is very pure; in other places it is mixed with foreign matters and passes into gneiss or chlorite-slate and is thrown up and much confused. It varies in structure from very large crystalline grains of pure carbonate of lime to a small grained saccharoidal appear- ance, which latter kind is used extensively for architectural purposes in Baltimore. Dolomite abounds in the limestone districts and passes into compact magnesian limestone ; in one locality a large grained variety, apparently pure, emits a very fetid odour when struck or rubbed. The following mitierals occur in the limestone: — Quartz, in detached masses and opaque crystals, is often disseminated. Fetid quartz also occurs in the limestone. Mica, in small spangles, in those limestones which appa- rently pass into gneiss. 110 MINERALS OF MARYLAND. Talc is most common in the dolomite. Tourmaline^ brown and yellow are occasionally seen. Tremoliie, white, in fibrous and radiated masses is common. Asbestiis, a seam or vein of this substance, extending for many yards, from 1 to 4 inches thick, in dolomite, was ex- posed recently by the excavations for the Susquehanna rail road. It is perfectly white and its fibres remarkably fine and soft. Augile, in white and grayish white crystals, rarely perfect, is very abundant in the dolomites. I have part of a crystal, (being as usual a flat prism) which is Ai inches long and 21 inches broad. Red oxide of titanium^ in crystals, is occasionally seen. Fetid, felspar^ semi-transparent, occurs in a fine grained limestone, at Scott's mills. Sulplmret of iron, in crystals, is often dispersed through the dolomites, and large pentagonal dodecaedrons are occasion- ally seen. Graphite occurs sparingly. The serpentine and associated tales enter the northern boun- dary of the State, a few miles west of the Susquehanna river, and are apparently in isolated and independent portions in gneiss and mica-slate. They are generally in a line running south-westerly through the State to the Potomac river, a little west of Rockville. It is probable that they are intrusive rocks, but have not been sufficiently investigated to permit more than a mere suggestion that such may have been the case. This formation embraces a variety of interesting minerals, which will be adverted to. Serpentine, both common and precious, (the latter most abundant near Gooptown) and of a variety of colours; it is opaque or translucent. Diallage, in lamellated masses, in all the localities. Talc, in every variety, but rarely in distinct crystals. The finest specimens are the lamellated masses near Gooptown, which present every shade of purple, rose colour, blue, and green. A beautiful translucent variety of a delicate apple green colour and foliated, occurs in serpentine, on the Gunpowder river, 23 miles north-north-east from Baltimore. MINERALS OF MARYLAND. Ill Liihoniarge, occuvs at 'Soldier's Delight' and Barehills; liiat of the former locality has all the variety of colour of the Coop- town talc. Asbestus, of the flexible varieties, most abounds at the Bare- hills, while the ligniform occurs principally at Cooptown. Hydrosilicates of tnaguesia occur at the different localities and furnish a material for the production of a large amount of magnesia and its salts. The proportions of the constituents of this mineral vary considerably. And as its external appear- ance is somewhat variable, some of the mineralogists of the present day, who cannot be satisfied unless each mineral has at least a score of names, have gratified themselves by favouring the scientific world with a goodly number of new names for this substance. It seems almost to graduate into opal on the one hand, and hydrate of niaguesia on the other. Both in appear- ance and composition ; in fact se7ni opal and the pure Ity- drate of tnagnesia exist in the serpentine formation. Hornhlend occurs at the Barehills in radiated masses in felspar, accompanied by radiated tremolite of a gray colour. Tourmaline^ in olive coloured crystals of a large size, exists at Cooptown, accompanied by a white opaque substance, in small crystals, whose nature has not been determined. Pitchstone occurs in a thin seam at Barehills. Aveiiturine felspar and beryl are noticed by Dr. Hayden,* on the eastern border of the serpentine at Barehills. A dendrilic appearance in the fissures of the magnesian minerals is very common, and beautiful specimens occur at the Barehills ; the dendrites are usually oxide of man- ganese. Ferroxide of chrome occurs throughout the serpentine. It was first found at the Barehills, in quantities sufficient for manufacturing purposes. But for several years past the ser- pentine of Harford counly, as well as that on the northern border of Cecil county and extending into Pennsylvania, yield the largest amount. Green oxide of chrome. At the last mentioned locality, a mineral of a beautiful bright green colour, compact, and liaving a smooth waxy aspect, occurs in very small quantities and has * Silliman's Journal, vol. 2-1, pp. 357, 358. 11^ MINERALS OF MARYLAND. not yet been analyzed, tt appears to be either a hydroxide of chrome or a hjdrosilicate. The oxides and acids of chrome enter largely into the composition of the colouring matter of the serpentine and its associated magnesian minerals, and with iron and magnesia produce their inniunerable varieties of beautiful shades and tints. Pyritous copper and magnetic oxide of iron occur at one spot, iu the Cooptown district, associated with ferroxide of chrome and talc in serpentine. Sulphuret of antimony has recently been found in the ser- pentine formation of 'Soldier's Delight.' It has been already remarked that the mica-slates most abounds in the north-western part of the primary region. It passes by imperceptible gradations into talcose slates, and pri- mary argillites, which are remarkable for their great uniformity and for the scarcity of mineral species in that part of this range within the limits of Maryland. Quartz, having a greasy lustre, is either disseminated in it, or forms veins, which are sometimes of considerable thickness and extent, and it contains no other mineral that has come to my knowledge, except sulphuret of w■o?^. In one place the sulphuret of iron has existed in abundance, but the greater part of it has become oxidated, and the rock presents precisely the appearance and is in the same relative geological position as part of the gold region of North Carolina. Of late years this metal has been traced from North Carolina, through Virginia, almost to our borders, and there is some reason io fear that it will eventually be found in this state ; an evil which it is to be hoped will be averted, because of the tendency that it would inevitably produce of drawing off the attention of the people from more useful and more profitable pursuits. The third division we proposed to extend from Parr's spring ridge to the foot of the Catoctin mountains, being the basin of the Monococy river. Parr's ridge has usually been considered about the line of separation between the primary and older transition formations, but in fact there is no line of separation. The mica slate absolutely alternates with and passes into the primary argillite, which itself by imperceptible changes passes into both roofing slate and compact blue lime- stone, decidedly transition. That portion of this division east MINERALS OF MARYLAND. 113 of the Monocacy river, consists of transition argiilite, em- bracing as subordinate rocks, a variegated silico-magnesian iiniestone, quartz rock, compact hornblend rock, and old red sandstone in its north-western part. Its minerals are Sulphiirel of copper^ (pure.) Carbonate of copper ^ (large and fine specimens.) Pyritous copper. Sulphiiret of lead. Specular oxide of iron. Oxide of manganese. Carbonate of Ihne in crystals. Sulphate of baryta. Quartz in crystals. Extensive quarries of roofing slate are opened in various parts of this district east of the Monocacy, and some of it is well adapted to its appropriate use. There is also an in- durated slate, which is easily wrought, resists the action of the weather so as to be used for tombstones and building. The copper ores, consisting principally of the carbonate and pure sulphuret, exhibit very favourable surface indications, iw. numerous localities between the villages of Newmarket and Taney town, and are always associated with the variegated limestone, which is not a continuous formation, but consists of isolated masses (without appearance of stratification) em- braced by the argiilite ; in one spot a spherical mass about forty feet in diameter, was completely enveloped by the slate and its existence only known in consequence of an excavation having been made for a road. Althougli the copper ores are associated with the limestone, yet thus far it appears to be most abundant in the adjacent slates. It does not appear in the mining of these ores, that the true vein has been dis- covered ; the ore exists in pockets, or is disseminated through the rocks. The whole appearance of the region induces us to think that valuable copper-mines will, at some day, be opened in this part of the country. Sulphuret of lead exists north of the village of Liberty, but has not been explored. Specular oxide of iron appears, scattered over the surface, in masses of fifty pounds weight and less, in the vicinity of 15 114 MINERALS OF MARYLAND. Liberty and is very abundant; the cavities are sometimes lined with imperfect crystals. Sulphate of baryta occurs in lamellated and amorphous masses. Fine crystals of calcareous spar were obtained from one of the mines, and among them I have a specimen containing apparently hemitrope crystals, whose form I have not been able to reconcile with the primitive form of carbonate of lime. Oxide of manganese is a constitu ent of a peculiar material of this district ; containing black oxide of copper, peroxide of iron, oxide of manganese, and earthy matters. This substance is in a friable condition, and loosely fills up cavities or veins in the slate. Crystals of quartz, usually white and more or less opaque, were obtained at some of the openings. It is to be regretted that the mining operations have been suspended; because, under judicious management, it is likely the profit of the owners as well as the cause of science would be promoted by their being continued. The limestone is compact, and presents various shades of green, red, and yellow, but the presence of silica renders it so hard, that the polishing is too expensive to admit of its being brought ex- tensively into use as an ornamental marble. In the northern part of the range a beautiful white marble has been dis- covered, which is exactly similar to the celebrated Carrara marble, A seam of anthracite^ about two inches thick, occurs near the Monocacy river, as I have been informed, but the character of the rock was not stated. The portion of our district west of the Monocacy, consists of compact blue limestone, clay slate, old red sandstone, and a calcareous breccia with an earthy ferruginous cement. The component masses of the latter vary in size from very minute to twelve inches in thickness, and in many instances they seem to have had their angles and edges rounded off by attri- tion, before they were cemented together. They have a great variety of colours and shades, such as brown, red, yellow, and white. When polished, they have a very rich appearance, as is exhibited in the columns of the representative hall, in the capitol of the United States. MINERALS OF MARYLAND. 115 A few miles north-west of the city of Frederick, there is a micaceous gray sandstone of the coal series, containing vegetable remains converted into coal. Beneath the sandstone these is a bed of shale, four or five feet thick. This is a coal field, geologically speaking ; but whether it contains productive beds can only be known by boring. The rocks have been much deranged, and a fault exists at the only spot where the shale has been seen. A pressure of other engagements renders it necessary to bring these notices to a close. In the next publication it is proposed to give some account of the minerals in the western parts of the iState, embracing the fourth, fifth, and sixth divisions. At present they will be briefly alluded to. The fourth consists of the Catoctin and South mountains and the narrow valley between them. Both of these moun- tains consist of primary rocks, composed of granular quartz, with epidote and chlorite, and covered by graywack, coarse gritstone, and amygdaloid. Middletown valley laying be- tween them, consists of argillite and chlorite slate. Pyritous and carbonate of copper are extensively disseminated in the rocks of the Catoctin mountain, and native copper has been seen, but I am not aware that there are indications of a true vein, or of a quantity of the ores likely to be of practical im- portance. The fifth division extends from the western base of the South mountain to the western base of Will's mountain, and has been supposed to belong exclusively to the transition series. It consists almost entirely of mountains, with the ex- ception of Hagerstown valley, about twenty miles broad, and a few other valleys of small extent. We are disposed to question whether the portion of this division, lying between Sideling hill and Evatt's mountain, does not belong to the older secondary or carboniferous era. There is, in fact, but little known of the mineralogy or geology of this division. It consists of the blue compact limestone, sandstones (red, gray, and white) with conglomerates, slates, shales, &c. Red sapphire, in minute grains or crystals, exists at the eastern base of the South mountain. Sulphuret of lead and iron, specular oxide of iron, and sulphate of baryta occur near Hancock. Anthracite, forming a productive, field has been 116 MINERALS OF MARYLANB, opened on the Virginia side of the Potomac, on Sleepy creek. An impure ferruginous limestone occurs a few miles west of Hancock, capable of producing a hydraulic cement, and at the eastern base of Will's mountain a material is found from which specimens of cement have been made, which appear to be fully equal to the celebrated Parker's Roman cement in the property of resisting the effects of water. The sixth division embraces all west of Will's mountain and consists of coal mines and the old red sandstone, on which they rest. The Frostburg coal region is the subject of a separate paper in this volume, and the portion of the State west of it has not been examined. We only know that the '■great icestern coal field? embraces the western parts of Mary- land. Sulphate ofharyta in nodules occurs in the Youghagany river, and fine crystals of quartz are found on the Meadow mountain; they are either limpid or beautifully clouded. Peroxide of Manganese rather ferruginous occurs a few miles east of the Youghagany river. The browti hematitic oxide of iron has not yet been referred to; it was omitted until the regions of country within our six divisions had been noticed. It does not exist in the first division, but occurs in independent beds, or is disseminated in beds of clay or loam, resting on the rocks of all the districts except the first. It occurs in many parts of Baltimore county, and more particularly on the borders of the primary limestones. Extensive beds of it, from 8 to 10 miles north of Baltimore, furnished ore to Hampton furnace for seventy years before they were exhausted, and the enhanced price of wood has prevented the opening of new mines that exist in the same region, of an ore that gives remarkably good metal. At the eastern base of the Catoctin mountain it exists in abundance; but the quality of the metal is injured by the pre- sence of the earthy phosphate of iron, which fills the cavities of the masses of ore. It is however worked at the Catoctin fur- nace and produces castings of good appearance. At this place it is associated with an ore of zinc, whose oxide forms incrus- tations in the upper part of the furnace, but we were unable to find any distinct specimens of the zinc ore. DETECTION OF ARSENIC. ll' Again, it occurs in the Hagerstown valley in several places, but has less of the external appearance of hematite, although it has the same composition. Both the brown and red hematite occur in the clay and loam which forms the surface of parts of the Frostburg coal region, the latter kind at the gap formed in the Savage moun- tain by Savage river. It having been thought desirable that this volume should contain an article upon the mineralogy of Maryland ; the writer has attempted to supply it by the foregoing notices, which are intended as a mere outline in order to give a general idea of the mineralogical character of the State, or rather of the eastern portions of it. The consideration of the western portion is the more willingly deferred, because the professional avocations of the writer, during the present year, will probably enable him to become better acquainted with its mineralogy. ARTICI. EVII. On the detection of Arseiiic in Medico Legal Investigations. By William R. Fisher. [Read before the Academy, Feb. U, 1836.] The form in which arsenic may be most readily adminis- tered intentionally as a poison, or accidentally, without any design to destroy life, in this country, is in the condition of white oxide, that being almost the only form in which it is accessible to the community at large. It is the white powder familiarly known as ratsbane or arsenic, and sold in all the shops, subject to no other restraint in its dispensation, than the conscience of the dealer may impose. There are, however, several preparations or forms, in which arsenic is found, in commerce and the arts ; — the white oxide of arsenic already alluded to, metallic arsenic commonly called cobalt or Jly- powder ; the red and yellow i^ulphurets, realgar and orpiment, and Fowler's solution, the arsenite of potassa. The latter of which may be employed as a poison, though more likely to be administered accidentally, as its composition is not generally known. A description here of these several substances is 118 DETECTION OF ARSENIC. omitted, my purpose being solely to demonstrate the means by which the arsenic they contain may be recognized in com- plex fluids, or mingled with organic matter. Instances have come within my observation where arsenic has been detected in soup, and iii bread. The processes by which the know- ledge of its presence has been ascertained and confirmed in those cases have been elsewhere detailed, and I shall presently proceed to demonstrate that the evidence which accumulated during those investigations, was such as forced upon me the conviction of its presence. It is deemed proper here to advert to the principles on which these experiments are based, and 1 shall occupy but a short space in laying down the few general laws involved in this examination. The only mode by which any substance may be discovered in a chemical analysis is by combining it with some foreign body called a test or reagent purposely introduced by the ex- perimenter, which by the exercise of affinity, or mutual rela- tion may either combine with the body which we desire to separate, or combining with that, by which the object is alrea- dy united, may by releasing it from its compound, occasion the separation, and consequent precipitation of the object of our search, either in an isolated or compound form. The ex- perienced chemist is generally sufficiently acquainted with the colour, form, and habits of the precipitates which he has occa- sion to produce to determine promptly whether that v/hich is yielded by his reagent is characteristic of the substance sought for, or if no particular object be sought, to judge what substance has been developed by his experiment. On this principle of precipitation by reagents are almost all processes for analysis conducted. Another process, however, and one which is essential to the separation of arsenic, is sublimation, directly the reverse of precipitation, and which is accomplished by the agency of heat, as in precipitation we avail ourselves of solu- tion in water. It can only be employed when the substance to be separated is not liable to be destroyed or decomposed at an elevated temperature. Where sublimation is employed, it may either be accomplished per se, or by the intermediate aid of reagents. This process as well as that of precipitation will be illustrated hereafter. For the ordinary purposes of investigation the production of one well known and characteristic precipi- DETECTION OF ARSENIC. 119 tate or sublimate is generally sufficient to establish the identity of any chemical body. But when human life itself may de- pend upon the colour, specific gravity, and other properties of a precipitate or sublimate, whose weight is scarcely appreciable by a delicate balance, it becomes an object of vast importance to be enabled to decide without the shadow of a doubt, on the identity of our results with the character of those compounds, which are produced when we apply our reagents to solutions containing certain known elements. Hence every possible care has been taken by toxicologists in describing those phe- nomena, which are most, nay, infallibly characteristic of the presence of arsenic, and they have not less carefully noted down the false lights by which our steps may be led astray, and our conclusions rendered incorrect by deductions from false facts. Premising then, that the experimenter who is engaged in a medico-legal investigation where poisoning by arsenic is sus- pected, should come to his task entirely unprejudiced, and with a calm, philosophic determination to note and observe facts as they occur and draw inferences fully warranted by the facts as observed, I proceed to arrange the tests by which his experi- ments will be performed, and to detail his manner of using them, describing at the same time the results which they pro- duce, and noticing the fallacies to which they may give rise. This caution of preserving an unbiassed mind, may perhaps excite a smile from those whose philosophic pursuits qualify their minds for the investigation of truth alone, but the remark is induced from having met with a recorded case, where cer- tain physicians in a country village having conceived that a brother practitioner had treated a patient incorrectly, took up the idea that the man had been poisoned by arsenic, and esta- blished, as they thought, the certainty of its presence by a post mortem examination and chemical investigation of the stomach and contents, to the satisfaction of a coroner's jury ; while, subsequently, a review of their analysis, by the medical gen- tlemen accused of malpractice, fairly demonstrated that the patient had died of ordinary inflammation of the bowels, and that a large dose of something which had been given him, and which the inquisitors thought or had heard was arsenic, was an ounce of sulphate of soda, which his physician had pre- 120 DETECTION OF ARSENIC. scribed. Counsel in one of our courts, have been known during a trial for poisoning, to apply the Scripture expression of 'seek and ye shall find,' to the chemists who were examined on the trial. Thus much in extenuation of the caution which has been given, to come to the examination totally unbiased. The pieces of apparatus required for such an analysis, are few and simple in their construction: they consist of a spirit lamp, test tubes, a funnel, two or three reducing tubes, a pair of small copper plates, and a small galvanic arrangement invented by Mr. Fischer of Breslaw. With this appareil and the necessary tests, which will be hereafter mentioned, the experimenter is provided with all the means necessary to a full examination of the suspected matter. His process is founded on the follow- ing facts : That certain reagents which he employs are known to produce precipitates of a particular colour and density with the salts of arsenious and arsenic acid: that the salts of these acids, when exposed in a reducing tube, with the black flux, (consisting of carbon and an alkaline salt,) are decomposed, the acid of the arsenic being reduced, and the metal sublimed in the upper portion of the tube, under a particular aspect; that compounds, containing arsenic, mixed with black flux, when heated between two copper plates, are decomposed, the metal being reduced and combining with the upper plate, forming an alloy of silvery whiteness ; and finally, that when a solu- tion containing a salt of arsenic is brought into contact with the poles of a galvanic battery, the salt is decomposed, the metal being reduced and found alloyed with the negative pole if it be susceptible of such a combination, or else simply coat- ing it. There is also another property peculiarly character- istic of arsenic, which is the odour exhaled, when arsenic, or any one of its compounds, is thrown upon burning coals. This odour has been compared to that of garlic, or phosphorus, and is generally described in the books, as alliaceous. It is so strongly marked, that when once smelled, it is scarcely possi- ble to forget it. Having thus explained the principles upon which the ope- rations about to be described are based, I proceed to specify the tests which are usually applied in the analysis of a fluid supposed to contain arsenic. They are ammoniacal sulphate of copper ; ammoniacal nitrate of silver ; sulphuretted hydrogen DETECTION OF ARSENIC. 121 gas, or water impregnated with that gas ; black flux, a com- pound formed by deflagrating nitre and cream of tartar; — all these furnish evidence so decided in its character that when they all concur, it is almost impossible that the experimenter can be deceived, in concluding that he has ascertained the presence of arsenic. But when having secured these precipitates, he sub- jects them to his reducing tube, Hhe experimentum cruciSy he finds again the characteristic appearances produced, his mind cannot fail to be convinced that he has in his hand the fatal agent, which has caused the death, perhaps, or severe illnes/ of some unfortunate victim to carelessness or design. The matter to be examined may be either food, which ban been poisoned, and a portion of which has been eaten, or r portion of that which having been swallowed has been ejected from the stomach, and is much mixed with fluids from the stomach. It belongs not to this place to describe the symp- toms or effects which, following the ingestion of a meal, should induce suspicion of poison having been taken. When the task of explaining what pertains to the duties of the chemist who is called upon after well grounded suspicions have been excited, has been undertaken, the examiner should first ascertain that due precautions have been observed in securing the sus- pected matter, especially if fluid, in a perfectly clean vessel, and that no opportunity has occurred for any admixture of a deleterious agent subsequent to its having been suspected, or before it is given into his charge. Having obtained this essential information a ready mode of deciding promptly whe- ther there be any reason for proceeding to an analysis, will be for the chemist to evaporate a small portion of the fluid, and to throw the resulting extractive upon burning coals. Should the alliaceous odour of arsenic be developed, it induces him at once to proceed to the employment of his liquid re-agents, and his experiments commence. If the subject of examina- tion be a simple colourless fluid it is filtered, and the filter care- fully washed with distilled water. The resulting clear solu- tion is then distributed among as many test glasses as it is pro- posed to apply tests, say three or four. To each he applies re-agents, which are appropriate to indicate the presence of arsenic, and if it be dissolved in the filtered solution, he finds that the ammoniacal nitrate of silver gives a bright yellow 16 122 DETECTION OF ARSENIC. precipitate, ammoniacal of sulphate of copper an apple green precipitate. The sulphurreted hydrogen gas, the solution being first slightly acidulated with a drop or two of muriatic or acetic acid, produces a bright yellow precipitate, which subsides upon the liquid being boiled. If these experiments be per- formed with due care, his mind in an ordinary case would be satisfied with the confirmation of his suspicions, but as his testimony may involve the fate of a fellow-creature, he pro- ceeds to investigate still further the character of his newly formed compounds. Either one or all the precipitates are care- fully separated from the fluid in which they are enveloped, by a filter, are dried, and being mixed with black flux, the mixture is introduced into the reducing tube, the powder adhering to its sides is carefully wiped away, and the end containing the mixture is heated in the flame of a spirit lamp to redness, this process as has been already said causes a decomposition of the arsenical salt if it be present; the metal is reduced and sub- limed within one half an inch above the flux, forming a bril- liant ring of a steel gray lustre ; when examined with a lens the inner crust appears a group of minute shining crystals. This crust may be sublimed higher up in the tube, and if the heat be adroitly applied the metal is converted into octahedral ' crystals of white oxide of arsenic. His opinion may be still further confirmed by re-dissolving the crystals last obtained, and applying the fluid re-agents de novo, when if the charac- teristic precipitates be again produced, no doubt can possibly exist of the identity of the subject of his examination with -ARSENIC. The process here related is a general sketch of a mode of procedure proper to be pursued in the examination of a simple colourless fluid, suspected of containing arsenic in some one of its forms ; but should it be required to examine a mass of solid organic matter under the same suspicions, some preparatory means must be employed to render the arsenic sensible to re- agents. The organic matter which has a tendency to embar- rass the experiments, and invalidate our confidence in the results must be destroyed, and this may be best accomplished by treating it with muriatic acid, boiling and evaporating to dryness repeatedly, until all appearance of organic structure DETECTION OF ARSENIC. 123 is destroyed, and nothing is apparently left but a black car- bonaceous mass. The effect of this operation is to deprive the animal or vegetable matter of its nitrogen, oxygen and hydrogen, and to leave the carbon, which is indestructible by these agents, with the arsenic, if any be present, diffused through it. It is perhaps necessary to suggest as a caution that the evaporation be conducted at a moderate heat, the arsenic may otherwise be volatilized and escape a subsequent examination. This metal if it have been introduced in the metallic form or fly-powder, or white oxide, rats-bane^ is by this action of the nitric acid, if any have been employed, con- verted into arsenic acid, a higher degree of oxidation than it has been supposed to possess in the first hypothetic case. In cases when the destruction of the organic matter can be accomplished without the use of nitric acid, I consider it decidedly preferable to omit it, for this reason, that its effect must invariably be to bring the arsenic into its highest state of oxidation, arsenic acid, a precipitate from which by sul- phuretted hydrogen is obtained with far less facility than from arsenious acid, or one of its salts. When brought into this condition, the next process is to lixiviate the carbonaceous mass, by triturating it well with boiling distilled water, which dissolves out the arsenic, or arsenious acid. The solution being now filtered, there exists for the purposes of experiment, the arsenical compound, in a simple almost colourless fluid, and the mode of rendering its presence apparent, is almost precisely the same as in the former case. To the solution thus obtained lime water should be added. The addition of which occa- sions a white precipitate of insoluble arsenite of lime. This arsenite of lime is to be dried, mixed with black flux, and the mixture submitted to the process for reduction and sublima- tion as before explained. It may be proper to mention here that if this process be conducted in a tube, open at both ends, we may have beside the deposite of crystals and the lus- trous ring, an aUiaceous odour, with fumes proceeding from the upper orifice. Another very satisfactory process, if we have obtained tlie solution of arsenic acid, in distilled water, is to test a portion of it with the ammoniacal nitrate of silver, when instead of a lemon yellow coloured precipitate, which followed its addition in the former case, we have one of a brick 124 DETECTION OF ARSENIC. red colour. The remaining portion of the solution may then be treated with sulphuretted hydrogen gas, or water containing that gas in solution, and the bright yellow coloured precipitate is thrown down, as shewn in the former example. This pre- cipitate, dried, mixed with the flux, and submitted to the re- ducing experiment, yields the ring, the crystals, and other characteristics of the metal, which will be readily recognized by an experienced operator. As preliminary to these more minute experiments, the carbonaceous mass, resulting from the action of the acids may be thrown upon burning coals, when the well known alliaceous odour will be exhaled if arsenic be present in the mass. The operations necessary under two forms, in which chemists may be called upon to show the presence of arsenic have now been detailed ; there are two general heads yet remaining, requiring attention. These are where arsenic may have been mingled with liquid food, as soup, tea, milk, &c. f Sca>/fi Arrarf//r^r^f.S^4( f?/"^^/^£r/? ^ I- 5i ^ I METEOROLOGICAL COMMITTEE. 143 H K C3- M •-1 S) CO 00 00 ^ -^ Ci Ci CJ1 Ol iK lU. 09 CO to to M i-i s ■^ O Oi O tn o ot o «n o Oi O Oi O Oi o en o C;i o o o o o o o o o o o o o o o o o O o w . . . p . P . . . . p . . . P to b^ 1— 1 (— 1 1— 1 b b b b b b b b b b o o b> o b> W lO — o CO M 03 Ol 4- CO i-" o o ^ to 4- OI Oi M CO SC M Oi w p— ' CO M Oi CO H- CO ■-» 4- Oi O) O to 4- Oi ^. hi to to to to to to to to to to to CC (X 00 00 00 OD 00 3' CO CO lO lO to — ■— H-1 H- o o o o o O O h- f-1 "- O O C5 *. 1— ■ C» Ol CO o M 4- to H- 4- M CO H- 4- M o . . . . p P o to 00 1— 1 H- 1 H^ >— < b b b b b b b b b b b b b b b 4- to h- O CO 00 02 OI 4- CO ^-^ o o ^— to 4- Oi Oi M 1— ' CO M ci tO O 00 Oi CO 1-1 CO M *• -J CO k- CO Ot OD 5' M Ot to O OO 03 4- h- CD M Oi Co 00 »-^ CO OI M CO >— 1— 1 O OD 0> Ol CO M- CO 00 Oi 4- Oi OO O to CO Ol M ^J 01 OD h- CO M O CO Ol CO H- 4- ^ O 00 CO H-i 00 Oi to K- o o O . . . . p to h^ ^^ ^u H^ '^ h> hi 't^ <^ b b b b b a h: h> 'a h> 4- CO ^-i O CO OD 03 Oi 4- CO — O O H- to 4* Oi Oi M CO 4- H- CO «5 4- to CO ^ 4- to CO -^ 4- M CO to 4- M CO ^. to -J CO CO 4- O Oi H- M CO Oi 4- CO 4- 00 to Oi t- Oi 3 O M 4- ^ ^ 4- ^ 00 Oi tO CO OI -^ o CO Oi CO CO Oi td Cit CO H^ O CO M Ol 4^ CO to O CO CO 4- OT ^ OO O h-i O o . . . . p . P to CD ^ h^ >^ 1— 1 b b b b b b b b b b h) '<^ h> o 'o >(- CO to o CO 00 <( CiT j^ CO to O O 1— ' CO 4- Ol Oi 00 Ol 4- I-' 00 CJ3 CO O 00 OI to O ^ Oi ^ o to Oi 00 o 5' 03 O 4- M 1— 1 4- 00 h- Ol OD to OI O M Oi CO Oi to CO CO 4- O Ol O 03 — ^ to ^ CO 00 OI o Oi CD 4- OO CO Ol O Ol O CO 00 to 03 O Oi CO CO M OD 4- O C;i — M CO O p O . . . . p *-4 1-^ k- 1 K^ b b b b b oh'hi 'i^ h> b b b b b CO ^ CO to >— * CO 00 ^ OI j:. CO to o o ►- CO 4- Oi Oi CC CO 05 CO O M 4- to CO Oi CO O ^ OT OD O Oi Oi CO to ^ CO 4- 0< M OO O I-' to 4- OI ^ I-* O OO ^1 OI 4- CO y t-i ^ — Oi CO CO M I— Ol CO CO "M HJ 4* O Oi to OO 4- O M C5 ^ M -^ h> b b b b b b h ' h> h> h> O^ CO to 1— < CO OD M Oi 4- CO to O O 1-1 CO 4- OT ^ 00 i-< en OI to CO Oi CO O M CO O ~1 Ol CD ^ 4- M O CO ^' -/ Oi CXi i-J 4- Oi CO — 4- Oi CO 1-1 4- CO O <» OI to O M 4- C3 Ol O Oi ►- ^ to 00 4- CO Oi O 4- CD CO QD to Oi ox . . . p o P O CO ^ ^ ^ H-< I-i b b b b ''^ C> hi '<^ '-^ ' ' '<=> '^ OI 4-- to H-1 O 00 M Oi 4- CO to O O h- CO 4- OI -J OO h-1 4- O M 4^ O M 4- ^ ^ 4. 1— I -^ OI OO 1— 1 OI 00 1-1 Oi HJ GC Ol to CO M 4- (-J CC Oi to CO CO Oi O) h-i 4 1 O 5' CFl 05 -J 00 CO O I-- to CO Cil Oi M 1-1 O CO OO ^ Oi 4- O O O CO 4- CC b> 'a CD '-^ b b b b b CO 0< 4- to 1—1 O 00 <( Oi 4- CO to O O 1-1 CO *^ en <» OD Ol CO CO Ol tO CO OI to 00 c;i H- 00 cji 00 to Ol CO to Oi H- • Ol 4- 03 — Oi kJ Oi >-' Oi K- Oi — 4- CD 4- CO 4- CO *. 3 CO Oi CO to to to k- h-» ta- C O' o o o O kJ ►-- >— 1 1— 1 M C3 O M CO O M 4. H- (X o to ^ *. Vt O CO Ci CO 01 ET- (B r^ P CT C P ^ ►Q P 3 r-^ ^ Ct> P^ O" H (^ (-*- CO :^ B (/2 fD P "^ >-»> ?3 CO to H p H ^ » ^ ci > H P a J5 ?3 t?d C CT- *^ » a. 144 REPORT OF THE METEOROLOGICAL OBSERVATIONS i MADE BY THE MARYLAND ACADEMY OF SCIENCE AND LITERATURE, On the 21st and 22d of June, 1836, at their Rooms, Baltimore, Lat. 39° 17' N. Long. 76° 36' W. Height of Barometer cistern 53ft-412 above mid-tide. n E- s 5 X s X S o O REMARKS. Cj O H O » P pj a o u o a DHY. WET ? June 21. 6 A.M. 29,722 63" 60.5 N. E. Light. Rain. 7 29,732 63 61 *( ti (< 8 29,747 63 61 (( s. w. CC Cirro-cumulus. 9 29.742 66 63 (C w. s. w. (( Cumulo strati. 10 29.744 69 65 N. N. E. s. s w. C( IC (( 11 29,754 71 66 N. E. Still. Cirro-cumulus. 12 29 750 73.5 67 S. E. E. S.E. None. Cirrus. IP.M. 29,744 74 67.5 ii W. Light. (( 2 29,743 72 66 E. S. E. W. N. W. 4C Cumuli. 3 29,749 69 64 E. by S. W. Moderate. « 4 29,763 69 65 N. E. W. by S. (C it 5 29,756 67 5 64 E. W. (( a 6 29,768 66 68 N. E. s. \v. 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